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A •'Q a r, ..'a , $ ague 0. g, ro ,1s � 0oc�oygo :3 g oho r,. < 5o • zaO y sof iA .2 00 S• co co 5 5 " A is ,OL' 8 p `q ° 04g. < 2, dA mr0. on' ' 9 cc).0 p 0 r. r� '° 'A•'PgoIcc $. co z. �' °. ° ccy , • 8,, S � ... 000a <..4 S � �N coa�'d " c c oo al •m O ErcoO qE. V6 om 6 eg cl"g 0r 8 Sid ° FEr ° � E$.mgg .; �e ° ya . <gs�'�p/•cLS' 1q1g. u '"�, H CD'< , cD , r•' W�! << cDA •, MCDdQ , toC- -'T �OA� oo ° �oA �ncop� ~• VI,c ommentS of ° Pa $ o0ocoac �� < dE ooticular interest to a P A . d N Z aPco o rrn ~. oEr.' ,Fo � o �••' », yr �' �° ~- r. .. � �the MPGA,accorg to Andrews,are c O 5' oo c ° coS S5 ° °� 5 ° �Cw g •aros `�those that offer or solutions to get- o $ ° • S ; a E. nR. b ~ E ~. 5'- ting rid'of wastAt this meetin ° o R' oc y' c'� in cb ° Eco y 6 o° czi,t ro�. 5 g E lthere was a_defe sentiment thata Ex'tiyD ►� ~• y5'S yA R,�,, ff.. Z v H § 1. O. k,' N � �,, O L: b vd0 A 9° fie' 2• N y�low, entombing the win specially-de- bfD4' 2. 5 1 1g § m;lig nsgie g o �D ,E ° ° BGo . CD $ 0 5' = $ ~ = '' signed landfills ld°be prefetred4 5' g. R. O ssomething that O -skid he.had not G f �" oo• R �s $ Ra y Q, E . 5Qa, $ �Iy Q�p eQ •7v ': cD o 5 aro A sn < O C 5' GF.+.ooQ OD g 1heard a lot of suprt fbr in the pasta �, o S Cr co F55oO a�e Q E wg co c Shi his presentn to the gather- * g S O $, G ? o g Qa °z;i mg on Wednesdatte said that the c g E • .5 a R & $ o 'd o P?'y a 5 ° cw '. tr E5 - MPCAhas beenuerthe impressio o,, ° ° inacSo 25y �~"'' $ ,° ,that public sentimt is against landfillandmase in for_of employing m < c,$ Z m means to break the waste down into ° i.,.: Ar� more natural components. � �" o• co � � . V� meeting, o handout�#vailable at the .� a � � � ;oo � ��, < ►, " �, � r.. y 5,°5° 5.�. � R• �• �co �,. � � y �''`<: C . g Proground wale;; 00 = 110, 00 1 ° i6'. a 0. a g .co E; E the waste is typically excavated and1101,g § sggs'86' 0go " Fo- 5 0a5 $ eri gc3' rn.either disposed of in a line landfill or �, " .2'K$ g p' °, 0 treated to destroy contaminant. Be- cause e . 25 rr � cause most of the contaminants can ~ be destroyed through burning, the preferred method for treating waste � is combustion.One way is to burn the ' ca.. "8 egngr .Fg2KR, • 1 15., o 0 g" 55 5 Fi; CD g Q 1" ft e. t4-' § ':' 11 co $ 5 5 cR5e ` e, y .1• BO 51150) a +� o, x= .... a ff. & g• s5' = g.4. 0, a CD, G. UN a co coo 9`<- 8609, r" . O ° r. • ' v '11 i E‘ M g i [ ?ki R p ' ' • . rroccp .-1 eoaE'S n " psi 5 nm. ate, .POkrv, gry 0:• A b' A '-'Iyr, 1' ', o neo $ .. ' �. lv'� NE - P. $ 'd $ . _ Z as -oo � _ a.. m• in •_ g �A 5 b � a+ g. el f�� g x O^ ir• . c P. o c. . 8.. co c'S ,•._ora w(.4 E.1. e °�, a'G ogA 4 a8 . 0�$. 8 $ `isg ,. a$ r+ o thsv A4liff • DATE UR..GHAS. l ER>Rlf PURCHASERDER 0 TYPE HB1 7 0 0 98 NORTHERN STATES POWER COMPANY Northern States Power Co. 414 NICOLLET MALL MAIL Accounts Payable Dept. SHIP TO: INVOICE P.O. Box 9366 MINNEAPOLIS MN55401 TO: > Minneapolis, MN 55440-9366 ATTN- Unless Otherwise Indicated Below MARK-FOR E-F U E L B Mail All Acknowledgments, And Correspondence Promptly To Northern States Power Company r- CITY OF OAK PARK HEIGHTS —1 FUEL SUPPLY P 0 BOX 2007 414 NICOLLET MALL 14168 NORTH 57TH ST MINNEAPOLIS MN 55401 STILLWATER MN 55082 1 PAGE 1 COFAKPB ................................................................................................ F. .B. NOT OT APPLIC ABLE tiND INE NO;<1f�UST:APPEA# Scheduled Terms: ON#.ALL PAPERS AN© PACKAGES. Delivery Date NET 98 01 05 / / 30 DAYS ................................................................................................. Account Or W.O. Number Requisition No. Requisitioner Buyer 03120 61 . 01 . 34. 44-00 D066459 SHIPTON ALLEN H DUANE L. RICHARDS Line No. Quantity Material Or Services To Be Furnished Price THE CITY OF OAK PARK HEIGHTS SHALL ACCEPT THE DISCHARGE BY NSP OF LEACHATE WASTEWATER ACCUMULATED AT THE A S KING ASH DISPOSAL SITE. THE CITY SHALL INVOICE NSP QUARTERLY FOR DISCHARGES, WITH QUANTITIES FOR THE QUARTER BASED ON DISCHARGE REPORTS SUPPLIED BY NSP. THIS PURCHASE ORDER APPLIES TO DISCHARGES DURING THE 1998 CALENDAR YEAR AND SHALL TERMINATE ON DECEMBER 31 , 1998. PLEASE DISREGARD THE ABOVE INVOICE MAILING ADDRESS AND SEND ALL INVOICES T0: NORTHERN STATES POWER COMPANY FUEL RESOURCES DEPARTMENT 414 NICOLLET MALL - REN SQ 10 MINNEAPOLIS, MINNESOTA 55401 PLEASE SIGN THE ACKNOWLEDGEMENT COPY AND n '@ gig y iEr RETURN TO NSP FUEL RESOURCES DEPARTMENT. U ATTN: AL SHIPTON FEB 8 pag8 � PAYMENT CANNOT BEGIN UNTIL THE SIGNED ACKNOWLEDGEMENT COPY HAS BEEN RECEIVED See Reverse Side For Additional Terms And Conditions Applying To This Order REV. 3/1/91 TAXES MATERIAL SUBJECT TO TAX OF STATE TO WHERE MATERIAL IS SHIPPED. ACTUAL FREIGHT CHARGES ARE GENERALLY TAX EXEMPT AND MUST BE SHOWN SEPARATELY ON INVOICE. TERMS AND CONDITIONS OF PURCHASE ORDER 1.0 The Seller shall manifest acceptanceis Purchase Order by executing the enclosrchase Order Acknowledgment copy and returning it to NSP Fuel SuDepartment, 414 Nicollet Mall, within 30 days of the "Purchase Order Date" noted on the front of this Purchase Order. Shipment of goods within 30 days of the "Purchase Order Date" shall constitute acceptance of this Purchase Order and satisfy this requirement. 2.0 This Purchase Order, including these Terms and Conditions, the Specifications, and any additional Terms and Conditions incorporated into and attached or referenced hereto, constitute the sole and entire agreement between the parties. Unless expressly accepted by NSP in writing, no other terms and conditions in conflict, or in addition to, those stated herein, shall be binding on NSP. 3.0 Unless otherwise specified, the price for goods and work includes all charges for packaging, boxing and crating, shipments shall be F.O.B. Origin and shall be routed in accordance with the attached routing instructions. 4.0 NSP shall have the right to cancel or suspend, by written notice, in whole or in part, this Purchase Order. Except in the case of termination for breach, allowance will be made for normal and reasonable expenses incurred by Seller prior to receipt of notice of cancellation, but NSP will not be liable for any charge or expenses incurred by Seller in advance of the normal or reasonable lead time necessary to meet scheduled delivery dates nor for any expenses, charges or liability incurred subsequent to the giving of notice of cancellation. For the purchase of this provision, Seller shall conclusively be deemed to have breached this contract in the event Seller becomes insolvent or commits an act of bankruptcy. 5.0 Seller shall, at its own expense, hold harmless and defend NSP against any claim, suit or proceeding brought against NSP which is based on a claim, whether rightful or otherwise, that the goods or services, or any part thereof, furnished under this Purchase Order, constitute(s) an infringement of any patent, copyright, or trade secret, and Seller shall pay all damages, costs, and expenses arising from such claim. 6.0 The Seller shall defend, indemnify and hold NSP harmless from and against all claims asserted by a third party (or parties), including employees of either NSP or Seller, and related damages, losses and expenses, including attorneys' fees, arising out of or resulting from Seller's performance of or failure to perform under this Purchase Order. 7.0 a) The Seller shall maintain Worker's Compensation Insurance and such insurance as will protect it and NSP from claims because of bodily injury, including death, and property damage which may arise out of or be connected with the performance of this Purchase Order, whether such claim arises out of the act, or failure to act or Seller or of NSP or of the direct or indirect delegee, appointee or employee of either of them. b) If Seller's employees or agents are to be on NSP's premises in the performance of this Purchase Order, the Seller shall maintain insurance written in the kinds and minimum limits of liability specified below. 1) Workmen's Compensation Statutory- Employer's Liability Limit - $100,000 each employee 2) Comprehensive General Liability Insurance Contractual to include coverage for Hold Harmless Agreement in Item 6 above Bodily-Injury -$100,000 each person $300,000 each occurrence Property Damage - $50,000 each occurrence $100,000 each aggregate c) If requested by NSP, the Seller shall file certificates of the aforementioned insurance with NSP on the Standard Minnesota AIA-AGC Joint Committee Form AA-701, or other form acceptable to NSP. 8.0 The Terms and Conditions provided herein and the rights of all parties hereunder shall be construed under and governed by the laws of the State of Minnesota. 9,0 The Seller warrants that all the goods and services furnished hereunder shall be produced and furnished in compliance with all applicable federal, state and local laws, orders and regulations. NSP shail have the benefit of all warranties implied at law, and all express warranties made by Seller. Unless otherwise specified herein, the Seller shall obtain all permits necessary for performance under this Purchase Order. 10.0 All goods and services shall be subject to NSP's inspection and acceptance or rejection within a reasonable time after receipt at NSP. The making or failure to make any inspection of, or payment for or acceptance of the goods and services shall in no way impair NSP's right to reject or revoke its acceptance of nonconforming goods, or to avail itself of any other remedies to which NSP may be entitled, notwithstanding NSP's knowledge of the nonconformity, its substantiality or ease of discovery 11.0 In making payments hereunder, NSP shall be entitled to conclusively presume that payment information furnished -�by:the C ii or, such as name, account number(s) and name of payee is accurate. In no event shall NSP make a ..t second payment where the first payment is made in accordance with such vendor furnished information. i. 12:0-NSP-personnel or assigned agents shall have the right of access to Seller's and Seller's major suppliers plant(s) for inspection of the goods and/or expediting purposes. As required by NSP, Seller shall supply schedules and progress .. ..--reports to NSP for use in expediting. 13.0 All provisions of Appendix I "Requirements Concerning Minority, Veteran and Handicapped Employment Opportunities" are hereby incorporated and made a part of the Terms and Conditions of this Purchase Order. 14.0 During the performance of this Purchase Order, the Seller shall be an independent contractor and not an agent of NSP. REV. 3/1/91 • r DATE PIJRCHA$)c;fl#3nEWNO • PURCHASE R D E R TYPE HB 01 /07/98 mmnPMafi.43.4ffliaR ........................................................ NORTHERN STATES POWER COMPANY Northern States Power Co. 414 NICOLLET MALL MAIL \ Accounts Payable Dept. SHIP T0: INVOICE > P.O. Box 9366 MINNEAPOLIS MN55401 T0: Minneapolis, MN 55440-9366 ATTN- Unless Otherwise Indicated Below MARK-FOR E-F U E L B Mail All Acknowledgments, And Correspondence Promptly To Northern States Power Company CITY OF OAK PARK HEIGHTS —1 FUEL SUPPLY P 0 BOX 2007 414 NICOLLET MALL 14168 NORTH 57TH ST MINNEAPOLIS MN 55401 STILLWATER MN 55082 1 PAGE 2 COFAKPB F.O.B. NOTAPPLICABLE ThtS RCHA$ ORD i NO Scheduled Terms: AND UN NUS AMI` APPEA#3 . ©ISI..ALL.;PAPES++�'.AND...PACK:AGES..:::::: i Delivery Date 1 NET 0 05 98 DAYS / 30 Account Or W.O. Number Requisition No. Requisitioner Buyer 03120 61 . 01 . 34. 44-00 D066459 SHIPTON ALLEN H DUANE L. RICHARDS Line No. Quantity Material Or Services To Be Furnished Price BY THE FUEL RESOURCES DEPARTMENT. See Reverse Side For Additional Terms And Conditions Applying To This Order REV. 3/1/91 TAXES NORTHERN STA ES POWE MATERIAL SUBJECT TO TAX OF STATE TO WHERE BY MATERIAL IS SHIPPED. ACTUAL FREIGHT CHARGES �[�J j ___ ARE GENERALLY TAX EXEMPT AND MUST BE SHOWN 7—" SEPARATELY ON INVOICE. AUTHORIZED SIGNATURE TERMS AND CONDITIONS OF PURCHASE ORDER 1.0 The Seller shall manifest acceptances Purchase Order by executing the enclosrchase Order Acknowledgment copy and returning it to NSP Fuel Sup Department, 414 Nicollet Mall, within 30 days of the "Purchase Order Date" noted on the front of this Purchase Order. Shipment of goods within 30 days of the "Purchase Order Date" shall constitute acceptance of this Purchase Order and satisfy this requirement. 2.0 This Purchase Order, including these Terms and Conditions, the Specifications, and any additional Terms and Conditions incorporated into and attached or referenced hereto, constitute the sole and entire agreement between the parties. Unless expressly accepted by NSP in writing, no other terms and conditions in conflict, or in addition to, those stated herein, shall be binding on NSP. 3.0 Unless otherwise specified, the price for goods and work includes all charges for packaging, boxing and crating, shipments shall be F.O.B. Origin and shall be routed in accordance with the attached routing instructions. 4.0 NSP shall have the right to cancel or suspend, by written notice, in whole or in part, this Purchase Order. Except in the case of termination for breach, allowance will be made for normal and reasonable expenses incurred by Seller prior to receipt of notice of cancellation, but NSP will not be liable for any charge or expenses incurred by Seller in advance of the normal or reasonable lead time necessary to meet scheduled delivery dates nor for any expenses, charges or liability incurred subsequent to the giving of notice of cancellation. For the purchase of this provision, Seller shall conclusively be deemed to have breached this contract in the event Seller becomes insolvent or commits an act of bankruptcy. 5.0 Seller shall, at its own expense, hold harmless and defend NSP against any claim, suit or proceeding brought against NSP which is based on a claim, whether rightful or otherwise, that the goods or services, or any part thereof, furnished under this Purchase Order, constitute(s) an infringement of any patent, copyright, or trade secret, and Seller shall pay all damages, costs, and expenses arising from such claim. 6.0 The Seller shall defend, indemnify and hold NSP harmless from and against all claims asserted by a third party (or parties), including employees of either NSP or Seller, and related damages, losses and expenses, including attorneys' fees, arising out of or resulting from Seller's performance of or failure to perform under this Purchase Order. 7.0 a) The Seller shall maintain Worker's Compensation Insurance and such insurance as will protect it and NSP from claims because of bodily injury, including death, and property damage which may arise out of or be connected with the performance of this Purchase Order, whether such claim arises out of the act, or failure to act or Seller or of NSP or of the direct or indirect delegee, appointee or employee of either of them. b) If Seller's employees or agents are to be on NSP's premises in the performance of this Purchase Order, the Seller shall maintain insurance written in the kinds and minimum limits of liability specified below. 1) Workmen's Compensation Statutory- Employer's Liability Limit - $100,000 each employee 2) Comprehensive General Liability Insurance Contractual to include coverage for Hold Harmless Agreement in Item 6 above Bodily-Injury - $100,000 each person $300,000 each occurrence Property Damage - $50,000 each occurrence $100,000 each aggregate c) If requested by NSP, the Seller shall file certificates of the aforementioned insurance with NSP on the Standard Minnesota AIA-AGC Joint Committee Form AA-701, or other form acceptable to NSP. 8.0 The Terms and Conditions provided herein and the rights of all parties hereunder shall be construed under and governed by the laws of the State of Minnesota. g.0 The Seller warrants that all the goods and services furnished hereunder shall be produced and furnished in compliance with all applicable federal, state and local laws, orders and regulations. NSP shall have the benefit of all:warranties implied at law, and all express warranties made by Seller. Unless otherwise specified herein, the Seller shall obtain all permits necessary for performance under this Purchase Order. 10.0 All goods and services shall be subject to NSP's inspection and acceptance or rejection within a reasonable time after receipt at NSP. The making or failure to make any inspection of, or payment for or acceptance of the goods and services shall in no way impair NSP's right to reject or revoke its acceptance of nonconforming goods, or to avail itself of any other remedies to which NSP may be entitled, notwithstanding NSP's knowledge of the nonconformity, its substantiality or ease of discovery 11.0 In making payments hereunder, NSP shall be entitled to conclusively presume that payment information furnished by the vendor, such as name, account number(s) and name of payee is accurate. In no event shall NSP make a second payment where the first payment is made in accordance with such vendor furnished information. 12.0 NSP personnel or assigned agents shall have the right of access to Seller's and Seller's major suppliers plant(s) for inspection of the goods and/or expediting purposes. As required by NSP, Seller shall supply schedules and progress reports to NSP for use in expediting. 13.0 All provisions of Appendix I "Requirements Concerning Minority, Veteran and Handicapped Employment Opportunities" are hereby incorporated and made a part of the Terms and Conditions of this Purchase Order. 14.0 During the performance of this Purchase Order, the Seller shall be an independent contractor and not an agent of NSP. REV. 3/1/91 411 n . _ ^ 41O AM REPORT ' ^ '_ Tuesday, Jan. 6, 1987 - - ' MINNESOTA POLLUTION CONTROL AGENCY (PCA) permits that would allow burning of unconventional fuels at six NEP plants are on public notice this month . The permits would allow incineration of unconventional fuels, such as waste oil , at the Sherco, Riverside, King-, High Bridge, Black Dog and Minnesota Valley plants. Permits also would cover proposals to burn soil contaminated with low- levet pesticides and hydrocarbons in a mixture with coal at the King plant and to Ancinerate spent activated carbon with coal at the Sherco plant . The PCA ` citizens ' board probably will consider the permits at its S»� Feb . 24 meeting . � 2'43 - ` � ' � °�^� ' � = p^°� "� ~ ' • • • • • � • AVA 4 Minnesota Pollution Control Agency •November 13 , 1986 Northern States Power Company 414 Nicollet Mall Minneapolis , Minnesota 55415 Attention: Mr . J. L. Kolar Senior Plant Regulatory Analyst Subject: Allen S. King Generating Plant Oak Park Heights, Minnesota, Incineration of Comtaminated Soils Thank you for your letter of October 9, 1986, in which you requested an amendment to your permit No. 202G-86-OT-1 to incinerate nonhazardous soils at your facility. The Agency is in the process of evaluating your proposal to allow incineration of on-site and off-site generated solvents and oils and also nonhazardous waste. This is a major policy change to our previous permits and the permit - amendments and will have to be approved by the Agency Board. However , in order to accomodate your time schedule to decontaminate the soils contaminated from the ANR Garrett Trucking Property in Roseville which have been determined nonhazardous by the Division of Solid & Hazardous Waste , we are issuing this letter of authorization in advance of the permit modification. Northern States Power Company is authorized by this letter to incinerate approximately 1, 500 cubic yards of soil contaminated with hydrocarbon and pesticide from the ANR Garrett Trucking Property in Roseville, Minnesota in the Unit No. 1 Power Boiler at this plant. The contaminated soil mixture' analysis shall comply with the waste oil and solvent specifications given in Part II.A. 8.d.1) of facility Permit No. 202G-86-0T-1 as established in the submitted analysis dated August 25, 1986. The analysis and amount incinerated shall be included in the existing sampling, analysis and reporting requirements of Part II.A. 8.d. 2 for on-site generated waste substances . Phone: 520 Lafayette Road North, St. Paul, Minnesota 55155 Regional Offices • Duluth/Brainerd/Detroit Lakes/Marshall/Rochester Equal Opportunity Employer III . Mr . Kolar November 13 , 1986 Page Two . For incineration of quanities of contaminated soil in excess of two (2) drums per day, the following boiler operational conditions shall be achieved and maintained when burning contaminated soil: 1) During the burn, the oxygen in the boiler fluegases shall not be less than three (3) percent measure on an instantaneous basis. 2) During the burn, the contaminated soil shall not comprise more than ten (10) percent on heat input or a mass basis of the total feed rate. 3) During the burn, the boiler shall be operating at normal furnace temperature with a minimum load of 50 percent of rated capacity. Your cooperation is most appreciated. Sincerely, T- 1 - 1 %---Q tia-6111-%-(- ig(Ce At: J. Michael Valentine Director Division of Air Quality JMV:dmc5. 36 cc: Richard Svanda Debra McGovern • Mins: 1/26/87 Annual Board of Review is scheduled for Wednesday, May 6, 1987 from 2 :00 P.M. to 4 :00 P.M. O 'Neal , seconded by Doerr, moved to rescind former motion in regard to burning contaminants at the NSP King Plant and rephrase making a motion to permit NSP to burn the contaminants. Roll call vote taken with ayes cast by Sommerfeldt and O'Neal, nays cast by Doerr and Torgerson with Seggelke abstaining. Doerr, seconded by Torgerson, moved to adjourn. 5 aye votes. Adjourned. • La Vonne Wilson Administrator/Treasurer r'` • • • i i CITY OF OAK PARK HEIGHTS MINUTES OF MEETING HELD MONDAY, JANUARY 26, 1987 Annual HRA meeting called to order at 7 :00 P.M. by Mayor Sommerfeldt. Present: Torgerson, Seggelke, Doerr, O'Neal, Eckberg and Wilson. O'Neal, seconded by Doerr, moved to retain same appointments as 1986 with the exception of Seggelke: Chairman - Sommerfeldt Vice Chairman - O 'Neal Secretary - Torgerson Executive Director - Seggelke Commissioner - Doerr 5 aye votes. Carried. On motion of Doerr, and seconded by Torgerson, HRA meeting was closed with 5 aye votes cast. Clerk read public hearing notice, presented affidavit of publication and mailing list on request for variance submitted by MTR Concepts. Mayor called for comments and discussion ensued. Doerr, seconded by O'Neal, moved to close hearing. 5 aye votes. Hearing closed. Seggelke, seconded by Doerr, moved to adopt Resolution #87-1-1 granting the above request for an 80 sq. ft. lot area variance. Roll call vote with 5 aye votes caste. Resolution adopted. Doerr, seconded by O 'Neal , moved to schedule public hearing Monday, February 9, 1987 at 7 :00 P.M. on request from MTR Concepts for rear yard setback variance. 5 aye votes. Carried. Public informational meeting was opened on request fr ,"Sa' `' Consulting Engineers and NSP. Mayor called for comments and discuss .on was held. Doerr, seconded by Torgerson, moved to close meeting. Aye votes cast by Sommerfeldt, Torgerson, O'Neal and Doerr. Abstain by Seggelke. Meeting closed. Doerr, seconded by Torgerson, moved to deny above request to burn contaminants at NSP King Plant. Roll call vote taken with aye votes cast by Doerr and Torgerson, nay votes cast by O 'Neal and Sommerfeldt and abstain by Seggelke. Doerr, seconded by O'Neal, moved to continue final approval on Swager Bros. 9th Addition to February 9 , 1987 with attorney' s to proceed with development agreement. 5 aye votes. Carried. • MAR-LEN, ANR SOIL REMEDIATION PRESENTATION NSP INCINERATION OAK PARK HEIGHTS CITY COUNCIL MEETING January 26, 1987 I. Soil Ingredients to be Burned Off a) Diesel Fuel in soils + AIR + Heat -> water vapor + carbon dioxide 2CH3 13CH2 + 23 02 -> 15 H20 15 2 CO2 b) Insecticide in soils + AIR + Heat -> water vapor + carbon dioxide (C12H8C16) + 16.8 02 63.2N2 -> 4 H2O 12 CO2 + hydrogen chloride + oxygen + nitrogen 6 HC1 2.8 02 10.5 NO2 II. Soil Volume/Mass to Place Into High Temperature Boiler at NSP Ring Plant: a) 1500 cubic yards or 2,430 tons of soil. III. Parameter Concentrations: a) Diesel Fuel: Test Average = 10.5 parts per billion (ppb) expressed as xylene. 10 .5 ppb = 10.5x10-9 lbs/lbs in the 1500 cubic yards of soil; 10.5x10-9 x 120 lbs/ft3 x 27 ft3/yd3 x 1500 yd3 = 0.051 lbs/1500 yd3 = 0 .82 oz/1500 yd3 = 1.64 tblspoons/1500 yd3 In the total 1500 cubic yards of soil or 0.011 tablespoons per 10 yd.3 truck load. b) Insecticide: Tests average = 11 .6 parts per billion (ppb) as insecticide 11 .6 ppb = 11.6 x 10-9 lb/lbs in 1500 cubic yards of soil 11 .6x10-9 lb/lbs x 120 lbs/ft3 x 27 ft3/yd3 x 1500 yd3 = 0.056 lbs/1500 yd3 = 0.90 oz/1500 yd' = 1 .8 tblspoons/1500 yd3 • In the total 1500 cubic yards of soil or 0 .012 tablespoons per 10 yd.3 truck load. IV. Harmful concentrations based on 'National Institute for Occupational Safety and Health" (NIOSH) September 1986 publication 'Regulations, Recommendations and Assessments Extracted from the Registry of Toxic Effects of Chemical Substances (RTECS) " . a) Diesel fuel expressed as xylene American Conference of Governmental Industrial' Hygienists (ACGIH) Threshold Limit Value (documentation of Threshold Limit Values for Chemical Substances in the Workroom Environment, Fourth Edition, 1980) ACGIH, TLV Time Weight Average (TWA) = 100 parts per million (ppm) = 100 x 10-6 lb/lb (This means at these concentrations laboratory test animals have developed narotic symptoms. ) Therefore, 100 ppm is 9 ,523.8 times greater a concentration than this soil contains at 10.5 ppb. b) Insecticide expressed as *chlordane. ACGIH suggests TLV-TWA no greater than 0.5 mg/m3 or approximately 14 .4 ppm. Therefore, 14.4 ppm is 1241.4 times greater a concentration than this soil contains at 11.6 ppb. * Chlordane is a commercial product sold over the counter for use as an insecticide. These application rates exceed 1 ,000 parts per million (ppm) for each application. Page 2 of 2 CITY OF OAK PARK HEIGHTS MINUTES OF MEETING HELD MONDAY, JANUARY 12 , 1987 Call to order by Mayor Sommerfeldt at 7 :00 P.M. Present: Torgerson, Seggelke , Doerr, O'Neal, Eckberg and Wilson. Clerk administered Oath of Office to Mayor Sommerfeldt , Councilman Doerr and Councilman Seggelke. O'Neal, seconded by Torgerson, moved to direct Clerk to submit letter to Lakeview Memorial Hospital showing the City' s support and recommending approval of Advance Life Support (ALS) . 5 aye votes. Carried. tritilk O'Neal, seconded by Doerr, moved to grant ;.' incinerate soil, contingent on a letter to the City with specific starting and completion dates and route schedules. With Mayor' s approval, NSP may then proceed with the project. Aye votes cast by Sommerfeldt and O'Neal. Nay votes cast by Torgerson and Doerr. Abstain by Seggelke. Motion defeated. O 'Neal, seconded by Doerr, moved to request an $8, 000.00 performance bond from Espree Corporation to complete painting at Oak Ridge Place. Completion date is set for July 1 , 1987. 5 aye votes. Carried. Seggelke, seconded by Torgerson, moved to schedule public hearing on request from MTR Concepts for variance on lot size at 5645 Penrose. Hearing to be held Monday, January 26, 1987 at 7 :00 P.M. 5 aye votes. Carried. Doerr, seconded by Torgerson, moved to schedule a Debt Service Study meeting for Tuesday, January 27 , 1987 at 7 :00 P.M. 5 'aye votes. Carried. Doerr, seconded by O'Neal, moved to set employee policy regarding schools and seminars within the seven county area, with tuition and mileage to be paid by the City. Meetings held out of this area -to include hotel accomodations. 5 aye votes. Carried. Doerr, seconded by O'Neal, moved to approve minutes of December 8th and 22nd. 5 aye votes. Carried. O 'Neal, :seconded by Seggelke , moved to send letter of commendation to Robert Choiniere for his years of service to District #834 Community Education Advisory Council. 5 aye votes. Carried. Doerr, seconded by Torgerson, moved to approve Home Occupation licenses for Mike Knutson and Mark Powell for the year 1987 . 5 aye votes. Carried. • i ! Evening Gazette,Jan.16,1987 NOTICE OF PUBLIC INFORMATIONAL MEETING dTY OF OAK PARK HEIGHTS NOTICE IS HEREBY GIVEN that a public informational meeting will be held by the City Affidavit of Publication Council of the City of Oak Park Heights with reference to the request of STS Consultants Ltd.to burn tainted soil(primarily diesel oil)in STILLWATER EVENING GAZETTE the Allen S.King plant in said city. Said informational meeting will take place STATE OF MINNESOTA ) on Monday,January 26,1987,at 7:00 o'clock COUNTY OF',NANESOT ON ))ss. P.M.at the Oak Park Heights Municipal Buil- • • ding, 14168 - 57th Street North, Oak Park ,Heights. John Easton,being duly sworn,on oath says that he is the publisher or authorized agent Dated this 14th day of January,1987. and employee of the publisher of the newspaper known as Stillwater Evening Gazette,and Is/La Vonne Wilson has full knowledge of the facts which are stated below: La Vonne Wilson City Administrator (A) The newspaper has complied with all of the requirements constituting1/16 qualification as a qualified newspaper,as provided by Minnesota Statute 331A.02,331A.07,and other ap- plicable laws, as amended. (B)The printed Notice of Public Informational Meeting Ke: City of Oak Park Heights which is attached was cut from the columns of said newspaper, and was printed and published once each week, for one successive dal Xv diKs; it was first published on Friday , the 16th day of January 19 87 ,and was thereafter printed and published on every -- to and in- cluding the -- day of -- 19 — and printed below is a copy of the lower case alphabet from A to Z, both inclusive, which is hereby acknowledged as being the size and kind of type used in the composition and publication of the notice: abcdefghijklmnopgrstuvwxyz BY: TIT : Publisher Subscribed and sworn to before me on this 16th day of January 19 87 • se14.6 " �. BEVERLY HARVIEUX e FirNOTARYPUBLIC-MINNESOTA 2 /r 1•c WASHINGTON COUNTY Notary Public My �. ••••••' Commission Expires Feb.28,1921 a RATE INFORMATION (1) Lowest classified rate paid by corn- t� � mercial users for comparable space • S (Line,word,or inch rate) (2)Maximum rate allowed by law for the Q 3 0 above matter S (� (Line,word,or inch rate) (3) Rate actually charged for the above matter S (Line,word,or inch rate) Received Payment 19 STILLWATER EVENING GAZETTE By 110 NOTICE OF PUBLIC INFORMATIONAL MEETING CITY OF OAK PARK HEIGHTS NOTICE IS HEREBY GIVEN that a public informational meeting will be held by the City Council of the City of Oak Park Heights with reference to the request of STS Consultants Ltd. to burn tainted soil (primarily diesel oil) in the Allen S. King plant in said city. Said informational meeting will take place on Monday, January 26 , 1987, at 7 :00 o' clock P.M. at the Oak Park Heights Municipal Building, 14168 - 57th Street North, Oak Park Heights. Dated this 14th day of January, 1987 . L. Vonne Wilson City Administrator • • 101 LAW OFFICES OF ECKBERG, LAMMERS, BRIGGS, WOLFF & VIERLING 1835 NORTHWESTERN AVENUE P. O. BOX C STILLWATER. MINNESOTA 55082 16121 439-2878 LYLE J.ECKBERG JAMES F.LAMMERS ROBERT G.BRIGGS PAUL A.WOLFF MARI4J.VIERLING January 14 , 1987 JAMES I.MOBERG VICKI L.GIFFORD Gazette 102 South Second Street Stillwater , Minnesota 55082 Re: City of Oak Park Heights Gentlemen: Enclosed is a Notice of Public Informational "•leeting on behalf of the City of Oak Park Heights . Please publish the same on Friday, January 16 , 1987 , and forward your Affidavit of Publication and statement to the Oak Park Heights City Administrator , La Vonne Wilson. • If there should be any questions, do not hesitate to contact us. Yours very truly, Lyle J. Eckberg LJE:kf Enclosure La Vonne Wilson P 411 w 2660 CIVIC CENTER DRIVE TELEPHONE 484-3371 O sevI MINNESOTA 55113 • January 15, 1987 Mr. Leonard Vanasse, President Mar-Len Development Corporation Suite 200 2500 West County Road C Roseville, MN 55113 Dear Mr. Vanasse: This letter is to confirm the City' s position with respect to its concerns relating to the minute amount of pesticides discovered on the Garrett site. Roseville's basic concern was related to its Development Agreement with Woodbridge Properties. In effect, the City did not want to become part of the chain of title when Garrett was purchased and subsequently written down for the developer. Albeit the problem was minute, it was the City' s intent that Woodbridge should continue to own the parcel until the problem was cleared up. The City did not place any restrictions on Mar-Len or Woodbridge with respect to removal of the building, asphalt modifications, etc. , as it related to the pesticide problem. Again, the City's basic intent was staying out of the chain of ownership title until the problem on the site was remedied in accordance with PCA guidelines. Sincerely, /4/'4,V - Craig A. Waldron Director of Economic Development • S Index to Information Regarding the Disposition of Contaminated Soils 1 . Estimate of quantity-of pesticides in.contaminated soil. 2. Disposition of large screened material from P.T. 3. Requirements of NSP for disposal. 4. Consultants request for disposal of large screened material. 5. Requirements of MPCA regarding incineration of material. 6. Consultants request to incinerate soil based on MPCA disapproval of Elk River Landfill as-a depository. 7. MPCA permission to move soil to Elk River Landfill. 8. Consultants calculation of quantity of soil to be removed. 9. Consultants request to amend application to MPCA regarding Elk River Landfill disposal. 10. MPCA position on disposal of soil. 11 . Consultants letter to Elk River Landfill detailing land disposal process. • 0 /, ,I _ , I , ,!1 ,I I i} i I t, I I --,. , 1 /a7-7r 7 -...-... 441.-41.14", .5... g 1.• S .; 8, i /4;2_9 1,14, 3 _ I / _ — 3. 7 /, .2.• /0 6.4, _ - 8,0 2 . / _ -”-- .! /6,6/ /2g,.1- /- 39, s- , 7_ - .0 H .......-. '=- ',I '1 -____ _-----', -_ I i ' I;I ;1 I 1 1 ife e" I / 1 ..---.- II •Z K' 4-442. CerYt,i-if-Age I Ai 4- / 11 __ _ _ .d. -/Le-- •Ch,re.e- #41-14 0 A-X 9442_ 0424 FL 40 4--t. ,lit,...t_ plj_c_le.„.f,,,/-,..6 ---- - -- I, - 11 40-44, 74e. 44 dr, . • I: ‘f-lerl'Le fa' Xatt7t0 Azi3 9 V,!..%) 4..r.1-7 • • Minnesota Pollution Control Agency "1100401 January 5, 1987 Mr. Bruce A. Bullock, Vice President ANR Freight System, Inc. P.O. Box 5070 Denver, Colorado 80217 Re: Disposition of Excess Material, ANR/Garrett Trucking Facility, Roseville, Minnesota (the Site) Dear Mr. Bullock: The Minnesota Pollution Control Agency (MPCA) staff have reviewed your request to place the 3/8" excess material in the excavated pit area at the ANR/Garrett Trucking Site. The chemical analyses of overburden materials and clay from the stockpile indicate that pesticide levels are low and should not pose a problem if placed in the pit. Therefore, the MPCA staff approve of your request to place the 3/8" excess material into the former excavated pit area. If there are any questions regarding this matter, please contact me at (612) 296-7745. Sincerely, (�J P.�f4 c")L /Ceta.tiYr Byron Adams Hydrologist Site Assessment Unit Site Response Section Division of Solid and Hazardous Waste BA:jb cc: Mr. Ross Ohman, STS Consultants Len Vanasse, Mar-Len Development Phone: 520 Lafayette Road North, St. Paul, Minnesota 55155 Regional Offices • Duluth/Brainerd/Detroit Lakes/Marshall/Rochester Equal Opportunity Employer 3 Northern States Power Company S P 414 Nicollet Mall Minneapolis,Minnesota 55401 Telephone(612)330-5500 December 3, 1986 Eric McGee Washington County Community Health Services 2000 Industrial Blvd Stillwater, MN 55082 NSP ALLEN S KING PLANT Request for Temporary Storage As we again discussed in some detail on December 2, approximately 1200 to 1500 yds3 of tainted soils are to be removed from ANR Trucking in Roseville to our NSP King Plant for high temperature incineration. Prior to final destruction of the soils, several project phases must be completed by STS Consultants, our regulatory department and the plant: • A letter of approval must be received from the Minnesota Pollution Control Agency. This approval was received on November 13, 1986. • Additional soil borings and analysis for pesticides and VOC's must be completed. This was completed on December 2, 1986. • Final screening of the soils must be completed for proper boiler operations. This phase is well underway and should be completed next week. • Employees at our King Plant will complete an Employee Right-to- Know/Safety Training session. This training will be completed as soon as our King Plant "outage" is over, hopefully by December 16, 1986. As you may now realize, several phases and schedules are required for this project that may necessitate our stockpiling a portion of the soils until incineration can be accomplished. Since our possible need to stockpile may exceed a two-week period, we understand that a Temporary Storage Permit to be required by your department. To expedite this requirement, please review this request and submit the necessary permit applications to the undersigned. Sincerely, vo4Plee J L Kola Sr Plan Regulatory Analyst ve cc rLeonard W Vanasse - Mar-Len Develop Corp _ Russ Ohman - STS Consultants • /( STS Consultants Ltd. N Consulting Engineers 'N 2405 Annapolis Lane,Suite 280 Minneapolis,Minnesota 55441 (612) 559-1900 December 18, 1986 Mr. Byron Adams Minnesota Pollution Control Agency 520 Lafayette Road St. Paul, MN 55155 Re : Dispostion of Plus 3/8" Excess Material , ANR/Garrett Trucking Facility, Roseville, MNS Dear Mr. Adams : Pursuant to our phone conversation December 15, 1986, I'm enclosing the chemical analysis data of the plus 3/8" mate- rial excavated from the former ANR/Garret Trucking facility. This excess material consists largely of miscellaneous rocks and clay. The chemical tests were run on composite samples taken from the rock oversize pile on November 25, 1986 and the clay stockpile sample taken November 26, 1986. Based on these low concentrations and the minimal degree of solubility of the pesticides in water, our client would like to place this material in the former excavated pit area. Please respond to our request expeditiously. Should you have any questions , please do not hesitate to call me at 559-1900. , Sincerely, STS CONSULTANTS, LTD. /245-44a -2-61 'a -teN,‘) Ross L. Ohman, Project Manager Environmental Services RLO/dn `t Enc. cc: Joe Davis, Mar-Len Development :e f. . • • - ..i. SERCO Laboratories St.Paui. Monescta•Cedar r i s loo,a 1931 West County Road C2.St.Paul.Minnesota 55113(612)636-7173 \ ®� O ) ADDENDUM TO REPORT NO: 2973 PAGE 1 12/18/86 Mar-Len Development DATE COLLECTED: 11/25/26/86 2500 West County Rd C DATE RECEIVED: 11/25/26/86 Roseville, MN 55113 COLLECTED BY: CLIENT C/O Ross Ohman PICKED UP BY: CLIENT STS Consultants Ltd. SAMPLE TYPE: SOIL SERCO SAMPLE NO: 109316 109836 SAMPLE DESCRIPTION: OVERBURDEN CLAY COMPOSITE FROM ANALYSIS: STOCKPILE Aldrin, ug/kg <1.0 <1.0 Chlordane, ug/kg <1.0 <1.0 Heptachlor, ug/kg <1.0 <1.0 Heptachlor Epoxide, ug/kg <1.0 <1.0 Lindane, ug/kg <1.0 <1.0 All samples were run consistent with EPA 608 methodologies. Report submitted by, 'v\ rit.ucc,41. (----A- Linda L. Crawford Project Manager < Means "not detected at this level" • • r.. A A { Minnesota Pollution Control Agency 1 • •November 13 , 1986 Northern States Power Company 414 Nicollet Mall Minneapolis, Minnesota 55415 Attention: Mr . J. L. Kolar Senior Plant Regulatory Analyst Subject: Allen S. King Generating Plant Oak Park Heights, Minnesota, Incineration of Comtaminated Soils Thank you for your letter of October 9, 1986, in which you requested an amendment to your permit No. 202G-86-OT-1 to incinerate nonhazardous soils at your facility. The Agency is in the process of evaluating your proposal to allow incineration of on-site and off-site generated solvents and oils and also nonhazardous waste. This is a major policy change to our previous permits and the permit amendments and will have to be approved by the Agency Board. However , in order to accomodate your time schedule to decontaminate the soils contaminated from the ANR Garrett Trucking Property in Roseville which have been determined nonhazardous by the Division of Solid & Hazardous Waste, we are issuing this letter of authorization in advance of the permit modification. Northern States Power Company is authorized by this letter to incinerate approximately 1,500 cubic yards of soil contaminated with hydrocarbon and pesticide from the ANR Garrett Trucking Property in Roseville, Minnesota in the Unit No. 1 Power Boiler at this plant. The contaminated soil mixture' analysis shall comply with the waste oil and solvent specifications given in Part II.A. 8.d.1) of facility Permit No. 202G-86-OT-1 as established in the submitted analysis dated August 25, 1986. The analysis and amount incinerated shall be included in the existing sampling, analysis and reporting requirements of Part II.A. 8.d. 2 for on-site generated waste substances . Phone: 520 Lafayette Road North, St. Paul, Minnesota 55155 Regional Offices • Duluth/Brainerd/Detroit Lakes/Marshall/Rochester Equal Opportunity Employer • • • Mr . Kolar November 13 , 1986 Page Two For incineration of quanities of contaminated soil in excess of two (2) drums per day, the following boiler operational conditions shall be achieved and maintained when burning contaminated soil: 1) During the burn, the oxygen in the boiler fluegases shall not be less than three (3) percent measure on an instantaneous basis. 2) During the burn, the contaminated soil shall not comprise more than ten (10) percent on heat input or a mass basis of • the total feed rate. 3) During the burn, the boiler shall be operating at normal furnace temperature with a minimum load of 50 percent of rated capacity. Your cooperation is most appreciated. Sincerely, J7t& LLP aik J. Michael Valentine Director Division of Air Quality JMV:dmc5. 36 cc: Richard Svanda Debra McGovern • • • . 4ae511F____ ; 1 rl/1 litZ! • • i .--/ N 0N 1 V \A\` •ice;-- . +4 ( Q oe ...........=:! son � I 4;f1 .. :._ :.•. ....... ....... . --...'-• 2 : :". .: .. .-..... -... .. ......-. . .-...... .. -. ........-. ,,. ..4 f� ..,..1. ts.:),>s Fri a) In-,,,f, 1 1 '='/W a a in o 0 ni � _ ;-Join E uUio t�1.13 0 o gt a i cn o G"+ UIN • Y •4. aE o WW 41 C , co . to yt70 �_zVQ • 0. Z G i • f • `. .• • • • PILE 44.1_ Co. CAT.. 'NOL CLASS. :304: STS Consultants Ltd. Consulting Engineers 2405 Annapolis Lane,Suite 280 Minneapolis,Minnesota 55441 (612) 559-1900 October 14 , 1986 Ms. Debra McGovern Minnesota Pollution Control Agency 520 Lafayette Road St . Paul , MN 55155 STS Project 93913 Re: Disposition of Pesticide and Hydrocarbon Tainted Soils, Former ANR Trucking Facility, Roseville, MN Dear Ms. McGovern: In response to the letter addressed to Mr. Bruce A. Bullock, ANR Freight Systems Inc. , dated September 12, 1986, from Mr. Gary Pulford , Chief, Site Response Section, MPCA, it is the intent of ANR Freight Systems Inc. to comply with Mr. Pulford' s concerns regarding the removal of the aforemen- tioned soils as addressed in the August 26, 1986 remedial action work plan. A modification to the work plan was requested to minimize the amount of possible leachate generation occurring in the open hole after excavation by backfilling the hole with clean material . This backfilling modification process , as re- quested, will take place subsequent to the evaluation of the pesticide and hydrocarbon analyses to be performed on the samples of the remaining soils in the excavation limits . This would allow for additional excavation in the event remaining soils contained pesticides or hydrocarbon contami- nation. However, during the interim while waiting for the chemical results , the side slopes and bottom area of the excavated hole will be covered with plastic . The excavated area will be designed as such to facilitate any water infiltration within the open excavation to be collected at a central location for removal by centrifugal pumping. The disposal of the pesticide and hydrocarbon excavated soils was intended for co-disposal at the Elk River Landfill . Permit requests were attempted but, due to the anticipated • volume of 1,200+ cubic yards and Elk River Landfill' s inade- quate management plan, the permit requests were denied by the MPCA Solid Waste Enforcement Unit. This denial alluded to Minnesota imilution Control Agency STS Projecipo. 93913 Ilk October 14, 1986 Page 2 co-disposal at any landfill due to certain MPCA policy changes regarding this alternative as discussed with Mr. Jerry Stanke, MPCA. Therefore, it has been decided that the excavated soils containing pesticides and hydrocarbons would be incinerated possibly by Northern States Power Company (NSP) . Mr. Jim Kolar representing NSP agreed that this soil material could be incinerated at 5% soil to 95% coal at the NSP King Plant, Bayport, Minnesota. This would allow for approximate- ly 99.99% destruction of pesticides and hydrocarbons within the soils at a temperature of 2400°F. This temperature is 600° in excess of the minimum temperature recommended by T.L. Ferguson, et al. , Midwest Research Institute for the destruc- tion of pesticides by incineration. ( 1) According to Mr. Kolar, the King Plant burns approximately 300 tons of coal • per hour and based on a 5% soil to 95% coal the anticipated disposal volume of 1,200 cubic yards would be disposed of in five days . It is proposed that the excavation process would begin Octo-'' ber 28 , 1986 and continue for approximately two days . The soils would first be screened so that particles no larger than 3/8 of an inch would be submitted for incineration. The remaining oversize non-absorbent rock would be delivered to a redi-mix plant for incorporation into a concrete mixture. On the final day of excavation, soil samples will be collected from the bottom and sides of the hole for analyses to deter- mine if the excavation limit is sufficient. Following the evaluation of this soil chemical analyses , additional excava- tion may be necessary or the clean excavated area will then be the responsibility of Woodbridge Properties . Within their fenced and locked area Woodbridge Properties will develop this site for various building structures . Should you have any questions regarding this disposition of soils please contact me by October 23, 1986 so we may be able to address your concerns before excavation begins. Sincerely, STS CONSULTANT , LTD. • Ross L. Ohman, Project Manager Environmental Services RLO/dn cc: Mr. Bruce A. Bullock, ANR Freight Systems Mr. Len Vanasse , Mar-Len Development Mr. Jim Kolar, NSP (1) Ferguson, T.L. , et al. [Midwest Research Institute] . Pilot scale incineration of pesticides. V. 2. Washington, U.S. Environmental Protection Agency, Office of Research and Monitoring , 1975. lv. (various pages) . 111 Minnesota Pollution Control Agency X)001 September 12, 1986 Mr. Bruce A. Bullock ANR Freight System, Inc. 1819 Denver West Drive, Building 26 Gol den,. .Col.orado 80401 Dear Mr. Bullock:' RE: Remedial Action Work Plan, Former ANR/Garrett Trucking Facility, Roseville, Minnesota Minnesota Pollution Control Agency (MPCA) staff have reviewed the STS Consultants Remedial Action Work Plan (dated August 26, 1986) for excavating pesticide-contaminated soils from the former ANR/Garrett Trucking Facility (Site). The proposal is approved with the following modifications: 1) the excavated areas should be backfilled with clean material to avoid leaching of any remaining contaminants to the ground water from rainfall or storm runoff: 2) the area of soil excavation where the north tank was removed, as designated on figure 1 of the August 26, 1986 Work Plan, should be expanded to the south and west to include soils under the middle of the tank that were found to be contaminated. Based on the information currently available to the Director of the MPCA, the Director of the MPCA hereby agrees not to take actions to prevent ANR/Garrett Trucking and STS Consultants Ltd. from undertaking the Work Plan of August 26, 1986, provided that this Work Plan is followed and the conditions set forth in this letter are met. The Director of the MPCA, however, specifically retains whatever rights he may have to stop these activities should they result in an imminent and substantial threat to the public health or welfare or the environment. This letter shall not be construed as an authorization under the Minnesota Environmental Response and Liability Act of 1984, Minn. Stat. ch. 1158 (1984) to conduct the activities under the Work Plan, nor shall it,to be construed as a release from any liability which ANR/Garrett Trucking, STS Consultants Ltd. has Phone: 1935'West County Road 82, Roseville, Minnesota 55113-2785 Regional Offices • Duluth/Brainerd/Detroit lakes/Marshall/Rochester • Equal Opportunity Employer • • Mr. Bruce A. Bullock • i Page 2 • J ' under any law, State or Federal . In addition, this letter shall not be construed as an assumption of liability by the MPCA for any activities undertaken by ANR/Garrett Trucking, STS Consultants Ltd., or their contractors or agents during the implementation of the Work Plan. The MPCA retains the right to require additional studies or remedial or removal actions at the Site if the Work Plan proves inconclusive or shows that hazardous substances continue to be released or have the potential to be released from the Site. Finally, the MPCA retains the right to seek reimbursement of its expenses incurred in connection with the Site. Please confirm in writing that the two modifications above are understood, and that they will be followed. Also, please submit a schedule for the completion of the Site Work .Plan at least 3 to 5 days prior to its initiation. Please be advised that all results from implementation of this Work Plan should be sent to the MPCA within thirty (30) days upon completion of the Work Plan, and no construction shall be initiated until MPCA staff have reviewed these documents. Correspondence, questions and comments regarding this Site or these procedures may be directed to Byron Adams of my staff at (612)296-7827. Since -ly, I ' 1 & ; 1 • Gary A. Pul • Chief Site Respon - Section Division of Solid and Hazardous Waste GAP:j b cc: Woodbridge Properties iiitg-Len Developers STS Consultants Ltd. r • iglho STS Consultants Ltd. Consulting Engineers 2405 Annapolis Lane,Suite 280 Minneapolis,Minnesota 55441 (612)559-1900 August 28 , 1986 Mr. Jerry Stahnke Minnesota ,Pollution Control Agency 1935 W. County Road B-2 Roseville , MN 55113 Re: Co-Disposal Request, Former ANR/Garrett Trucking Facility, Roseville, Minnesota Dear Mr. Stahnke: Subsequent to our receiving the chemical analytical results of the soil samples retrieved from within the tank excavation area located at the above-referenced site, we have revised our estimate of soils needing co-disposal . The proposed excavation areas are outlined in Figure 1. The approximate amount of soil needing co-disposal is 1500 cubic yards of pesticide tainted soils and approximately 1000 cubic yards of hydrocarbon tainted soils . These soils will be removed within the areas outlined in Figure 1. These quantities are estimates only and may not necessarily be realized. On-site field observation and chemical soil sampling will be done during and after the excavation respectively to verify the extent of remediation. Also, please be advised that the generator of this soil is ANR Freight System, Inc. , P.O. Box 5070 , Denver, Colorado 80217. The contact person is Mr. Bruce A. Bullock, vice president and legal counsel . It is requested that your files be updated to incorporate this change. Should you have any questions, please do not hesitate to contact me at 559-1900. Thank you for your assistance. Sincerely, STS CONSULTANTS LTD. A41011-- Ross L. Ohman, Project Manager Environmental Engineering Services RLO/dn j t - . / 1 • • 7061= • 1 V II• 3 • • •tat%.ti{r. ` 'ef{s{ii~:. ,: i;:;:•: ti.t,••i;.: • • oil i j:.:• •a.. iiiii iii..1 I 0 1 {f is'i' '•:::�••:•:: :<� In I all 13 1 a'::iii: §.1:. {:i:i�•':= i=.aia: '.tii 0) t O - ::i i'::i:{is:i::..1..1:t=iff? • -& 3 • :::::_ `t • :: _ 0 130 1 NI = N O•▪If l ::.:1471%.:',:r,::::.i s � Oj" .xl. .1, a OAli __ . _ I Oils' • /���d�/�i��� 1 moi' ; �1J• 1 • 1 \\ I 1 V : i 0 0 , 1 I 73 % K `� -'� N jn --7 N CO 1 • w 1 ..1. 1 -• PF •A IV W 1 (p y O ■ • O O 9 N I 1 N 0 Cleveland-Avenue--- - . m 17;441 • • . n fill . r- Z . a • •0 O C • . C 0. 0• C) m • Z a � 3 -. co y —. 0. a o 2 X 003 I ' E, go P. � a , = m °' m a 3 a) a, ,, a � .< -< 03 CO N 0io 0 /A co 11.Q 116 STS Consultants Ltd. Consulting Engineers 2405 Annapolis Lane,Suite 280 Minneapolis,Minnesota 55441 (612)559-1900 August 12, 1986 Mr. Bill Regan Minnesota Pollution Control Agency 1935 West County Road B-2 Roseville, MN 55113 Re : Co-Disposal Request Amendment for Mar-Len Development Dear Mr. Regan: Subsequent to the removal of two underground diesel fuel tanks at the former ANR/Garrett Trucking Facility in Roseville, Minnesota sandy soils containing slight amounts of diesel fuel were observed. These soils seemed to be limited to the areas immediately adjacent to the tanks. The cause of this soil contamination appeared to be a slight pin hole in the 12,000 gallon diesel tank. This was corroborated by the Roseville Fire Chief, Mr. Bruce Ryden, and by Mr. Byron Adams of the Minnesota Pollution Control Agency. Therefore, in order to protect human health and the environ- ment, Mr. Byron Adams requested these soils be removed in conjunction with the excavation of the pesticide tainted soils located near the tank excavation. It is estimated that there exists an additional volume of 1,500 to 2,000 cubic yards of sandy soil containing small amounts of diesel fuel. The intent is to dispose of these soils along with the pesti- cide soils as per the co-disposal request dated July 24, 1986 , thus increasing the maximum disposal volume of approxi- mately 2,500 to 3,000 cubic yards. Should you have any questions regarding this amendment re- quest, please do not hesitate to contact us at 559-1900. Thank you for your assistance. Sincerely, ST CO SULT TS, L Ross L. Ohman, Project Manager Environmental Engineering Services RLO/dn , is 49;1 Minnesota Pollution Control Agency X)CP1 . RECrIvED July 2, 1986 JU" :l 44,6 Mr. William Keppel W. . •ellim Dorsey & Whitney t 2200 First Bank Place East L. Minneapolis, Minnesota 55402 Dear Mr. Keppel: RE: CENTRE POINTE BUSINESS PARK DEVELOPMENT CLEVELAND AND COUNTY ROAD C, ROSEVILLE, MINNESOTA As a follow-up to our meeting on June 26, 1986, I have summarized the discussion on the contamination problems at the proposed Centre Pointe Business Park site in Roseville, and of the Minnesota Pollution Control Agency (MPCA) staff's recommendations on dealing with the contamination. This letter serves as a written confirmation of the MPCA staff's position on these issues. Our meeting began with a discussion of how the contamination was discovered at the proposed development site. Northwestern Bell reported diesel fuel in a manhole along Cleveland Avenue to the MPCA. Mr. Kevin Faus of the MPCA determined that the fuel may have originated from the Garrett Freight Lines' refueling area, just west of Cleveland Avenue. When soil samples were taken near the fuel pumps, Mr. Faus noticed a strong pesticide/herbicide odor. Laboratory analyses showed minor hydrocarbon contamination; however, low concentrations of several pesticides were also detected. The highest levels of pesticides were found in a soil boring very close to a crack in the pavement on the Garrett property near the pumps. The pesticides may have been leaked or spilled from Garrett trucks, and were then washed into the soil through the crack in the pavement. It is difficult to know assuredly that this was the cause, since there had also been a hog farm on this site years ago. The primary topics of conversation at the meeting were: the locations of contamination found at the site, the areal extent and magnitude of contamination, and actions to remedy the contamination situation. Three separate areas of contamination found on the proposed development site were discussed. Based upon the available information, the MPCA staff believe that remedial actions are only warranted at the area near the Garrett fuel pumps. Phone: 1935 West County Road 82, Roseville, Minnesota 55113-2785 Regional Offices • Duluth/Brainerd/Detroit Lakes/Marshall/Rochester Equal Opportunity Employer Jr • t "' Mr. William Keppel Page 2 There was a consensus at the meeting that the PCB contamination found north of County Road C-2 and the diesel fuel contamination near the Northwestern Bell manholes along Cleveland Avenue do not require any remedial action. The concentrations were too low to be of any major concern. The pesticide contamination near the Garrett fuel pumps, on the other hand, was significant enough to warrant some response. Though the pesticides in the soil do not constitute a hazardous waste, the pesticide Heptachlor Epoxide was found in ground water at a level that is at least 1,000 times greater than the recommended safe drinking water concentration. All parties agreed that the contaminated soil should be excavated and either treated or disposed of on the site. The MPCA staff made several recommendations for the proper handling of the pesticide-contaminated soil. We requested that these concerns be addressed in a written proposal for site remediation. These recommendations are: 1. Excavate contaminated soil in the area of soil borings CA5 through CA12. The excavation should be deep enough to remove the soil shown to have pesticide contamination in the SERCO lab analysis reports. 2. When the Garrett Freight Lines diesel fuel tanks are removed, the underlying soils should be observed for contamination. If contamination is apparent due to odors or visible staining, then samples should be collected to assess the extent and levels of contamination. If pesticides and/or diesel fuel are found, this soil may require excavation and proper disposal or treatment. Please notify Byron Adams or myself prior to the tank removal, so that we may be on-site to observe the integrity of the tanks and adjacent soil conditions. 3. The contaminated soils in the area of soil borings CA5 through CA12 should be disposed of or treated on-site. Disposal would involve placement of the material as fill, well above the water table, and covering with asphalt. Treatment would involve thin-spreading the material in an appropriate location on-site to allow decomposition of the pesticides over a long period of time. A treatment proposal should include at a minimum: description of treatment site soil conditions; application rates; addition of chemicals or agents to facilitate treatment (type and frequency) ; soil tillage to promote pesticide decomposition; and site monitoring. 4. Three monitoring wells should be installed in,the area of the pesticide contamination. One well should be hydrologically upgradient and the other two wells should be downgradient from the contamination. The wells should be sampled quarterly to determine whether pesticides are contaminating ground water in this area. If no contamination is found after sampling for approximately one year, the wells may be abandoned according to the Minnesota Water Well Construction Code. Mr. William Keppel Page 3 /////r _ 40-id 0.6, 5. A brief discussion of the contamination problem and remedial actions taken should be attached to the property title at the time of sale. We understand that a detailed proposal, which addresses the above recommendations will be sent to the MPCA within the next several weeks. Please submit this proposal to the attention of Debra McGovern, Supervisor, Site Assessment Unit. We appreciate your cooperation in this process. If you have any questions concerning the contents of this letter or in preparation of the plan for site clean-up, please contact me at 296-7745 or Byron Adams at 296-7827. Sincerely, 772i4.14 Michael Connolly Site Assessment Unit Site Response Section Solid and Hazardous Waste Division MC:sg cc: Jack Vandenorth, Briggs & Morgan Craig Waldron, City of Roseville . , 4 July 17, 1986 Mr. Chris Kreger Elk River Sanitary Landfill 22191 Highway 169 N.W. Elk River, MN 55330 STS Project 93913 Re: Co-Disposal Request Dear Mr. Kreger: Please find enclosed a completed MCPA Co-Disposal Request Form for the co-disposal of soils. This soil will be gene- rated from an excavation process at an office park develop- ment in Roseville , Minnesota. The reason for proceeding with the co-disposal process is due to low concentrations of pesticides found in the soils from an earlier farming opera- tion. Mr. Bill Regan and Mr. Tom Griese of the MPCA have indicated to me that co-disposal of this material is a viable alternative. The MPCA is only concerned with total concen- trations of these pesticides. Therefore, I am forwarding to you copies of the analytical resuls of the soil samples col- lected. The area to be excavated would encircle soil borings CA-5, CA-8, CA-9, CA-10, and CA-11 as indicated in the at- tached figure. The amount of this material excavated is calculated to be approximately 1,000 cubic yards. This material will be delivered to your facility via my client' s hauler. In order to expedite the co-disposal process, please send the completed MPCA disposal form back to me as soon as possible. Upon receiving your approval, I will then deliver the co- disposal form to the MPCA for their final endorsement. Should you have any questions, please do not hesitate to contact me at 612/559-1900. Sincerely, STS CONSULTANTS, LTD. Ross L. Ohman, Project Manager Environmental Services RLO/dn Enc. J 2• • . . • 4111 Minnesota Pollution Control Agency _ REQUEST FOR CODISPOSAL OF Solid and Hazardous Waste Division NONHAZARDOUS INDUSTRIAL WASTE 1935 West County Road B2 Roseville, Minnesota 55113 ) Read instructions on attached sheet. This is an official request of : ' Company Name to dispose of nonhazardous industrial waste at: Landfill Name Elk River Landfill Waste Name/Description Landfill Permit Number Soil with law conc. pesticides SW-74 830929 A Process Which Produces Waste ` Quantity and frequency of Disposal Soil excavation for building site One time • Packaging: JJ Bulk Q Drums Q Bags/Cartons R Open H Sealed W Other (specify) several truck loads Physical state: 51 Solid El Liquid p Semi-Solid . Properties Evaluated: Attach laboratory reports, Material Safety Data Sheets, and/or sited references. 51 Non-ignitable l Non-reactive Fl Non-oxidative Flash point ' NA o pH I NA Toxicity Oral LD50 NA Dermal LD50 • NA Inhalation NA EP Acid Leach Test ASTM Water Leach Test Parameter* (mg/1) (mg/1) Arsenic (As) Barium (8a) Boron (B) Cadmium (Cd) Chlorides (Cl) Chromium (Cr+S) . COO Copper (Cu) NA Cyanide (CM-) �.. Fluoride (F) Iron (Fe) Lead (Pb) _ Manganese (Mn) Mercury (Hg) Nickel (Ni) Nitrate (NO3) , _ Oil and Grease _ _. .__.__. Phenol (C4HgOH) Selenium (Se) Silver (Agg) Sulfates (SO4) TOS Zinc (Zn) Endrin Lindane Methoxychlor ? Toxaphene 2,4 0 2,4,5-TP PCB PQ-00303-02 *Please attach actual laboratory data sheet (see attached analysis) • 410 -3- Landfill Certification: I certify that this request of (landfill name, permit number) to accept and dispose, if approved by the Director, 's (company name) nonhazardous industrial waste is complete and that to the best of my knowledge and belief the information contained herein is true and accurate. I understand that this request for disposal must be approved by the Director before disposal will be allowed. Signature - Title Date Typed Name, Address, and Telephone Number o Authorized Ufficial PQ-00303-02 . .._ 41 . - . dr SERCO . 1931 West County Road C2 - St.Paul,Minnesota 55113 (612)636-7173 LABORATORY ANALYSIS REPORT NO: 994 PAGE 1 05/27/86- -•• Subterranean Engineering Corp. DATE COLLECTED: 6875 Highway 65 N.E. DATE RECEIVED: 05/01/36 P.O. Box 32308 COLLECTED BY: CLIENT Minneapolis, MN 55432 PICKED UP BY: CLIENT Attn: Michael R. Simac, P.E. SAMPLE TYPE: SOIL SERCO SAMPLE NO: 29066 29076 29086 29096 29106 SAMPLE DESCRIPTION: CA4 CA5 CA5 CA5 CA6 #1 #1 #2 #3 #1 ANALYSIS: 12 - 14 0.3-3.5 5.0-10 11.5-12 11.5-15 Benzene, ug/kg <10 - <10 <10 ,Toluene, ug/kg <10 - - <10 <10 "Xylene, ug/kg <10 _ _ 11 <10 FID Scan, ug/kg as Hydrocarbons <100 - - 170 <100 Aldrin, ug/kg - 30 12 5.2 - a-BHC, ug/kg - <1 .0 <1.0 <1.0 - ' b-BHC, ug/kg - <1.0 <1.0 <1.0 d-BHC, ug/kg - <1 .0 <1.0 <1.0• - g-BHC, ug/kg • - <1.0 <1.0 <1.0 - Chlordane, ug/kg - 98 37 <1.0 - 4,4' DDD, ug/kg - <1 .0 <1.0 <1.0 - 4,4' DDE, ug/kg - <1.0 <1.0 <1 .0 - 4,4' DDT, ug/kg - <1.0 <1.0 <1.0 - Dieldrin, ug/kg - <1 .0 <1.0 <1.0 - Endosulfan I, ug/kg - <1.0 <1.0 <1.0 - Endosulfan II, ug/kg <1.0 <1.0 <1.0 - Endosulfan sulfate, ug/kg - <1 .0 <1.0 <1.0 - Endrin, ug/kg - <1.0 <1.0 <1.0 - Endrin aldehyde, ug/kg - <1 .0 <1.0 <1.0 - Heptachlor, ug/kg - 3.8 <1.0 <1.0 - • Heptachlor Epoxide, ug/kg = 91 <1.0 8.1 - "Toxaphene, ug/kg - <10 <10 <10 - Polychlorinated Biphenyl, (PCB), 1016, - <10 <10 <10 - ' (3 ug/kg Approved by:43 < means "not detected at this level" continued • SANITARY ENGINEERING LABORATORIES, INC. tn 0 • OW SERCO 1931 West County Road C2 St.Paul,Minnesota 55113 (612)636-7173 LABORATORY ANALYSIS REPORT NO: 994 PAGE 2 i 05/27/86- SERCO SAMPLE NO: 29066 29076 29086 29096 29106 SAMPLE DESCRIPTION: CA4 CA5 CA5 CA5 CA5 #1 #1 #2 #3 #1 ANALYSIS: 12 - 14 0.3-3.5 5.0-10 11.5-12 11.5-15 Polychlorinated Biphenyl, (PCB) , 1221 , - <10 <10 <10 - ug/kg Polychlorinated Biphenyl, (PCB) , 1232, - <10 <10 <10 - ug/kg Polychlorinated Biphenyl, (PCB) , 1242, - <10 <10 <10 - ug/kg Polychlorinated Biphenyl, (PCB), 1248, - <10 <10 <10 - ug/kg Polychlorinated Biphenyl, (PCB) , 1254, - <10 <10 <10 - ug/kg Polychlorinated Biphenyl, (PCB), 1260, - <10 <10 <10 - ug/kg • SERCO SAMPLE NO: 29116 29126 29136 29146 29155 SAMPLE DESCRIPTION: CA7 CA8 CA8 CA9 CA10 #1 #1 #3 #1 #1 ANALYSIS: 11.5-15 0.0-5.0 11.0-13 0.0-5.0 0.3-2.0 Benzene, ug/kg <10 - <10 - Toluene, ug/kg <10 - 10 - - Xylene, ug/kg <10 - <10 FID Scan, ug/kg as Hydrocarbons <100 - <100 - - Aldrin, ug/kg - <1.0 <1.0 33 5.4 Approved by:G, < means "not detected at this level" continued SANITARY ENGINEERING LABORATORIES, INC. it) III • • SERCO 1931 West County Road C2 St.Paul,Minnesota 55113 (612)636-7173 LABORATORY ANALYSIS REPORT NO: 994 PAGE 3 05/27/86- SERCO SAMPLE NO: 29116 29126 29136 29146 29156 SAMPLE DESCRIPTION:. CA7 CA8 CA8 CA9 CA10 #1 #1 , #3 #1 #1 ANALYSIS: 11.5-15 0.0-5.0 11.0-13 0.0-5.0 0.3-2.0 a-BHC, ug/kg - <1.0 <1.0 <1.0 -------- b-BHC, ug/kg - <1 .0 <1.0 <1.0 <1.0 d-BHC, ug/kg - <1.0 <1.0 <1.0 <1 .0 g-BHC, ug/kg - <1.0 <1.0 1.9 <1 .0 Chlordane, ug/kg - <1 .0 <1.0 <1.0 <1 .0 4,4' DDD, ug/kg - <1.0 <1.0 <1 .0 <1.0 4,4' DDE, ug/kg - <1.0 <1.0 <1.0 <1.0 4,4' DDT, ug/kg - <1.0 <1.0 <1.0 <1 .0 Dieldrin, ug/kg - <1.0 <1.0 <1.0 <1.0 Endosilfan I, ug/kg - <1 .0 <1.0 <1.0 <1.0 Endosulfan II, ug/kg - <1.0 <1.0 <1.0 <1.0 Endosulfan sulfate, •ug/kg - <1.0 <1.0 <1.0 <1.0 Endrin, ug/kg - <1 .0 <1.0 <1.0 <1.0 Endrin aldehyde, ug/kg - <1.0 <1.0 <1.0 <1.0 Heptachlor, ug/kg - <1 .0 2.9 3.7 8.0 Heptachlor Epoxide, ug/kg - ,\22 <1.0 <1.0 <1.0 Toxaphene, ug/kg - <10 <10 <10 <10 Polychlorinated Biphenyl, (PCB), 1016, - <10 <10 <10 <10 ug/kg Polychlorinated Biphenyl, (PCB), 1221 , - <10 <10 <10 <10 ug/kg Polychlorinated Biphenyl, (PCB), 1232, - <10 <10 <10 <10 ug/kg Polychlorinated Biphenyl, (PCB) , 1242, - <10 <10 <10 <10 ug/kg Approved by: -.6::, means "not detected at this level" continued SANITARY ENGINEERING LABORATORIES, INC. • • NoiirSERCO • 1931 West County Road C2 - St.Paul,Minnesota 55113 (612)636-7173 LABORATORY ANALYSIS REPORT NO: 994 PAGE 4 05/27/86- SERCO SAMPLE NO: 29116 29126 29136 29146 29156 SAMPLE DESCRIPTION: CA7 CA8 CA8 CA9 CA10 #1 #1 #3 #1 #1 ANALYSIS: 11.5-15 0.0-5.0 11.0-13 0.0-5.0 0.3-2.0 -------- Polychlorinated Biphenyl, (PCB) , 1248, - <10 <10 <10 <10 urs/kg Polychlorinated Biphenyl, (PCB) , 1254, - <10 <10 <10 <10 ug/kg Polychlorinated Biphenyl, (PCB) , 1260, - <10 <10 <10 <10 ug/kg SERCO SAMPLE NO: 29166 29176 29186 29196 29206 SAMPLE DESCRIPTION: CA10 CA11 CA12 CA12 CA13 #4 #3 #1 #3 #2 ANALYSIS: 10.0-11 7.0-9.5 0.3-2.0 7.9-9.0 2.0-5.0 Benzene, ug/kg <10 <10 - <10 ' - Toluene, ug/kg <10 <10 - <10 - Xylene, ug/k <10 <10 - <10 - FID Scan, ug/kg as Hydrocarbons <100 <100 - <100 - Aldrin, ug/kg <1.0 <1.0 <1.0 <1.0 <1.0 a-BHC, ug/kg <1.0 <1 .0 <1.0 <1.0 <1.0 b-BHC, ug/kg <1 .0 <1.0 <1.0 <1.0 <1 .0 d-BHC, ug/kg <1.0 1.8 <1.0 5.6 <1.0 g-BHC, ug/kg • <1.0 <1 .0 <1.0 <1.0 <1.0 Chlordane, ug/kg <1.0 <1.0 <1.0 <1.0 <1.0 4,4' DDD, ug/kg <1.0 <1.0 <1.0 <1 .0 <1.0 Approved by: 7 < means "not detected at this level" continued SANITARY ENGINEERING LABORATORIES, INC. OVi F: ' ' • • SERCO 1931 West County Road C2 St.Paul,Minnesota 55113 (612)636-7173 LABORATORY ANALYSIS REPORT NO: 994 PAGE 5 05/27/86 - SERCO SAMPLE NO: 29166 29176 29186 29196 29206 SAMPLE DESCRIPTION: CA10 CA11 CA12 CA12 CA13 #4 #3 #1 #3 #2 ANALYSIS: 10.0-11 7.0-9.5 0.3-2.0 7.9-9.0 2.0-5.0 4,4' DDE, ug/kg <1.0 <1.0 <1 .0 <1.0 <1.0 4,4' DDT, ug/kg <1.0 <1.0 <1.0 <1 .0 <1 .0 Dieldrin, ug/kg <1.0 <1 .0 <1.0 <1.0 <1.0 Endosulfan I, ug/kg <1.0 <1.0 <1 .0 <1.0 <1 .0 Endosulfan II, ug/kg <1.0 <1.0 <1.0 <1.0 <1 .0 Endosulfan sulfate, ug/kg <1.0 <1 .0 <1.0 <1 .0 <1 .0 Endrin, ug/kg <1.0 <1.0 <1 .0 <1.0 <1.0 Endrin aldehyde, ug/kg <1.0 <1.0 <1.0 <1.0 <1.0 Heptachlor, ug/kg <1.0 <1.0 <1.0 <1 .0 <1.0 Heptachlor Epoxide, ug/kg <1.0 <1.0 <1.0 <1.0 <1.0 Toxaphene, ug/kg <10 . <10 <10 <10 <10 Polychlorinated Biphenyl, (PCB), 1016, <10 <10 <10 <10 <10 ug/kg Polychlorinated Biphenyl, (PCB) , 1 221 , <10 <10 <10 <10 <10 ug/kg Polychlorinated Biphenyl, (PCB), 1232, <10 <10 <10 <10 <10 ug/kg Polychlorinated Biphenyl, (PCB), 1242, <10 <10 <10 <10 <10 ug/kg Polychlorinated Biphenyl, (PCB) , 1248, <10 <10 <10 <10 <10 ug/kg Polychlorinated Biphenyl, (PCB) , 1254, <10 <10 <10 <10 <10 ug/kg Polychlorinated Biphenyl, (PCB) , 1260, <10 <10 <10 <10 <10 ug/kg Approved by: 4.7.0." means "not detected at this level" continued SANITARY ENGINEERING LABORATORIES, INC. !" .. . .. .. ,.. ID • SERCO 1931 West County Road C2 St.Paul,Minnesota 55113 (612)636-7173 LABORATORY ANALYSIS REPORT NO: 994 PAGE 6 05/27/86- -A SERCO SAMPLE NO: 29216 29226 29236 29246 29256 SAMPLE DESCRIPTION: CA13 CA14 CA15 CA16 CA16 #3 #4 #4 #1 #2 ANALYSIS: 5.0-9.5 4.5-8.9 6.5-15 0.3-2.0 2.0-6.5 Benzene, ug/kg <10 <10 <10 <10 <10 Toluene, ug/kg <10 <10. <10 <10 <10 Xylene, ug/kg <10 <10 <10 <10 <10 FID Scan, ug/kg as Hydrocarbons <100 <100 <100 <100 <100 SERCO SAMPLE NO: 29266 SAMPLE DESCRIPTION: CA16 #4 ANALYSIS: 9.0-12 � Benzene, ug/kg <10 Toluene, ug/kg <10 Xylene, ug/kg <10 FID Scan, ug/kg as Hydrocarbons <100 All analyses were performed using EPA or other recognized methodologies. Report submitted by, Anne L. Ochs Project Manager < means "not detected at this level" SANITARY ENGINEERING LABORATORIES, INC. P'T • 411 • m ea _ m 2m N a em Os C m = m 0 r >. '•VI n m '- o073 t 13 sj C Q — W el m e e"0 "� c G C Y n m m - y c Z `r° om = m OWrn p ^ . C LS = U a 3 Q 0 • ■ 1,•N., o 0 co 0 J O z � cc I' Z : ! i r 1 c 1 i anuany puelana�o \�"i�II m i a 3 • • Cr h I 1 • - - ---- _ -• O- ...0. 7 S --- - --- ---_. i ,=• ® L I N O � 1 �/ 1 N < /w,� I I .. • O �al 01 W I 0 , } 1 • • 1 P 1 I . ,sp 0o ` � o . .a C� m I -si• CI 1•: ;uA 0 y ` 13 ai;AV: . Ccis 1 _ Y..O - m L I 1. g i• 'fr: x r 4,0 it 0. • t • • G . $: ' - 'x _ :r'Ll-:4. I k $.`;r,7r.c :.::Gam':'':]: _e:`•rma • 0 s' 'C3 ife.Vallikt&rrar•41NiC C :: c.-• :l:f▪lr: • • \ -.It': .,,V...u.1,:; - \ iir A "It' • • The following are chemical excerpts from The Merck Index 9th Edition, 1976. Please note the concentrations of the pesticides found in the co-disposal soil is approximately 6,000 times less toxic than the Merck Index indicates is a lethal dose in rats. III - 215 Aldehol• lylnortoxiferine;diallyltoxiferine. [C„HS0N403]2+. Prepn of the latter. Structure: Tait et aL.Experientia 10, 132(1954); a p. dichloride and diiodide: Boller et aL. U.S. pat. 3,080,373 . Hely. Chim. Acta 37, 1200 (1954). Crystal structure and (1963 to Hoffmann-La Roche). molecular conformation: Duax,Hauptmann, J.Am. Chem. w Dichloride, C61H50Cl2N,02, N,N'•diallylnortoxiferinium Soc.94,5467(1972). Total synthesis: Schmidlin et aL.Hely. S (I dichloride,Ro 4-3816,Alloferin. Crystals from methanol or Chim. Acta 40, 1438 (1957); Johnson et aL. J. Am. Chem. ethanol. Compd contains 5 moles of water of crystn after Soc. 80,2585(1958). Three-step synthesis from corticoste- y equilibration in air,[a]tt—348'(methanol);uv max(meths- rone: Barton.Beaton, ibid 82,2640(1960);83,4083(1961). fc 1 nol): 292 nm(e 43,000). Synthesis of the intermediates: Johnson, Johns, U.S. pat. I. Diiodide. C6,H3OI2N4O2, solid. uv max (methanol): 291 •3,049,539{1962 to Wisconsin Alumni Res.Found.). Alter_ nm(e 39,900). nate route to total synthesis: Johnson et aL,.1.Am. Chem, C, THERAP CAT: Dichloride as skeletal muscle relaxant. Soa 85, 1409 (1963). Biosynthesized in the zona glomera_ 215. Aldehol. Oxidation product of kerosene Manuf: lora and transported chiefly by albumin. In man. 400 „g Bider, James. Chem. Met. Eng. 35, 156 (1928). CA. 22, secreted normally in one day. Secretion influenced by b 1845'(1928). ACTH, growth hormone, plasma sodium and potassium. t and the renin-angiotensin system. Causes reabsorption of 8 Colorless liquid;disagreeable odor. d about 0.825. Dis- tills between 200-290', Na+, Cl-,and HCO3' and diuresis of K . Review: L F. 6 USE For denaturing alcohol. Reser, M. Reser, Steroids(Reinhold. New York, 1959) pp 701-720. �- 216. C14-Aldehyde. 2-Methyl-442,6,6-trimethyl-1-cy- I clohexen-I-yl)-3-butenal; allo-6-C14 aldehyde: x,2,6.6-tet- , h ramethyl-l-cydohexene•3-butenal. C14H230; mol wt OH CH2OH 206.32. C 81.50%, H 10.75%, 0 7.76%. Usually prepared Ju from 8-ionone and methyl or ethyl chloroacetate: Miles et O—� i 3 aL, J Am. Chem. Soc. 70, 1584 (1948); Stieg, Gillis. U.S. a u _. . pat. 2,987,550 (1961 to Pfizer); Oediger et aL, Bar.97, 549 CE 5 C i (1964). May also exist in its isomeric form a,2,6,6-tetra- 1 I methyl-1-cycloherene•2-butenal, named also a,2,6,6-tetra- s methyl-I-eydohexene-l-crotonaldehyda !! o n 41111411 I •- ;E3 r Hydrated crystalst Y from•dilute acetone.mp 108-112'(when 8 Ca_CECHCEO H3C anhydr mp 164'). [0.]p +152.2'(anhydr,c = 2 in acetone). CE3 [0.]p +161'(c=0.1 in chloroform). uv max: 240 nm(log e 53C • 4.20 for the monohydrate;e,,,,,, 15,000 for the anhydr). 21-Acetate, C HJ006, flat needles from acetone + ether, mp 198-199', [ale +121.7'(c = 0.71 in chloroform). Syn- thesis: Wettstein et aL;Jeger. U.S. pats. 3,002,972 and Crystals from cooled pentane, mp about 0'± 1.0'. bpt 6 3,014,029(both 1958 to Ciba). I 103-110'.du 0.956. nD 1.5112. uv max: 232 nm(EI% 967). Minimum observable activity of the free alcohol in the USE: In the synthesis of vitamin A. urinary sodium retention assay occurs at between 0.05 and 217. Aldicarb. 2-Methyl-2-(methylthio)propanal O.- 0.01 y per rat, while at least 16 y of desoxycorticosterone • acetate is required for the same level of activity. it f(methylamino)carbonyljoxime; 2•methyl-2-(methylthio)pro- •HSP CAT: Adrenocortical steroid. pionaldehyde 0.(methylcarbamoyl)oxime;UC 21149;Temik. THERAP CAT (VET): Adrenocortical steroid, mineralocor- r C7H74N2025;mol wt 190.25. C 44.19%,H 7.41%.N 14.72%. ticord 0 16.82%, S 16.85%. CH3SC(CH3)2CH=NOCONHCH1 Synthesis:' Payne et aL.J.Agr. Food Chem.14,356(19661. o'izv r&PI,2,3,4,10,10.Hexachloro-1,4,4a,5,8,8a- 1 1 " - CH-labeled synthesis: Bartley et aL,ibid 604. Metabolism: herahydro.1,4:5,8-dimethanonaphthalene;compd 118:Octa- Bartley et aL.ibid 18,446(1970). Mass spectrum: Benson. lene. C221-13C1,3; mol wt 364.93. C 39.50%. H 2.21%, Cl k Damico. J. Assoc. Offra AnaL Chem. 1968, 347. Review: 58.30%. Prepn: pat-2,635,97o e Romine. AnaL Methods Pestis Plant Growth ReguL 7, 147- Schmerling. U.S. pat. 2,911,447 (959 o(Un ve sal Oil 162(1973). Prod.). Synthesis: Korte.Rechmeier,Ann.656, 131 (1962). Crystals from isopropyl ether. mp 99-100'. Soly at 25' (w/w)in water: 0.6%d acetone: 35%;benzene: 15%;xylene: Cl 5%; methylene chloride: 30%. LD30 orally in female rats: C1 i I mg/kg,Weider et aL.J.Econ EntomoL 58, 154(1965). USE: Insecticide,acaricide,nematocide.. I CE2 CC121 - Cl i 218. Aldol. 3-Hydroxybutanal 3-hydroxybutyraldehyde; t acetaldol. C4H3O2; mol wt 88.10. C 54.53%, H 9.15%. 0 Cl 36.32%. CH3CH(OH)CH2CHO. Manuf by condensation of acetaldehyde in aq NaOH: Alheritiere, Gobron. US. pat. Crystals.mp 104'. Very sol in most organic solvents and - 2,713,598(1955 to Usines de Melle). insol in water. Stable in presence of organic and inorganic Colorless,thick liquid. d16 1.109. bp30 83';dec about 85'. alkalies; stable to the action of hydrated metal chlorides. 1 Miscible with water,alcohol,ether. LD3a orally in rats: 2.2 Compatible with most fertilizes, herbicides.fungicides and 1i g/kg. Toxic Substances List.H.E.Christensen,Ed.(1974)p insecticides. Can be formulated as an emulsifiable concen- f 166. trate, oil soln, and in dusts. LD30 orally in rats: 39-60 USE: Manuf rubber vulcanizers, accelerators and age re- mg/kg, Gaines. ToxicoL AppL PharmacoL 14, 515 (1969). sisters;in perfumes;ore flotation. USE: Insecticide. Caution: Poisoning may occur by inges- THERAP CAT: Hypnotic.sedative. don, inhalation, skin absorption. Severe symptoms may 219. Aldosterone. 115,21-Dih result from ingestion or percutaneous absorption of 1 to 3 g. ydroxy3,20-dioxopregn- especially in presence of liver disease. Acute toxicity: renal 4-en-18-al; 3.20-diketo.110.18-oxido-4-pregnene-18.21- damage. tremors. ataxia, convulsions followed by CNS diol;elektrocortin;electrocortin;aldocortin. C21H2/O3;mol wt 360.44. C 69.97% H 7.83%,O 22.20%. Adrenocortical depression, respiratory failure. death. Chronic toxicity: steroid which exerts re aro prolonged exposure may cause hepatic damage gul ry influence on metabolism of electrolytes and water. Isoln: Simpson et aL.Experientia 9, 221. $-Aletheine. 3-Amino-N-(2_mercaptoethyl)pro- 333(1953); Hein Chim.Acta 37, 1163(1954);Mattox et aL. panamide; N-(8-alanyl)-8-aminoethanethiol; N-$-alanyl-2- J.Am. Chem.Soc.75,4869(1953); Hannan et aL, ibid 76, mercaptoethylamine: N-(8-alanyl)-2-aminoethylmercaptan. 5035 (1954). Solutions contain an equilibrium mixture of C3HJ2N2OS;mol wt 148.23. C 40.51%,H 8.16%.N 18.90%, the aldehyde and the hemiacetal, the equilibrium favoring 0 10.79%, S 21.63%. H:NCH2CH:CONHCH2CH2SH Page 32 Consult the cross index before using this section. i I t1, —.- � L.,: 1- v. + t 5' r t• 2 c'",', r `.{'- 4,;`4.--,,,.;'_-.• i Ir .f.. �; • r '$ 'N :sa.#� .t: } < o w.f•�r,p"' 0. 4.'0', a.-.y.} y.,. , E '�k' +r..` r, c�`^S} ,..,„ �, r o,, i it-., f u 7.,‘,_.,1_,._ �'�,1_ i,.:r 'tea t�'> .t' ... �{ '�. - TIT t•♦ r yk )' .J 5 • t .zt v1-ill Chlordecone 2053 i• q toluene. xylene, petr ether. Resistant to acid and alkaline Dihydrochloride. CISH73C13N2. prisms from alc + ether. i hydrolysis. Strong oxidizing agents convert it to the corre- mp 216-216.5'. Freely sol in water, sol in alc. Aq soln is `,# sponding sulfoxide and sulfone. acid to litmus. LDS*i.p.in mice: 137 mg/kg.Castillo et al.. ;! `i 1 USE: Acaricide. esp for the control of eggs and larvae of J. PharmacoL Exp. Ther.96,388(1949). I: ii red spider mites. Caution: May be irritating to skin. Kid- Di[(terr-butyl)naphthalene sodium sulfonate]. C4H31CI- { si ney and liver injuries have been produced in exptl animals. N,Na206S:. Bexedan- I THERAP CAT Antihistaminic. 3 2048. Chlorbenzoxamine. 1-[2-[(2-Chlorophenyl)phen- 1 THERAP GAT (VET): The hydrochloride as antihistaminic ., , ylmethoxy)eth yl]-4-[(2-methylphen y!)methylJpiperaz i n e; s�� c I 1-[2-(o-chloro-a-phenylbenzyloxy)ethyl]-4-o-methylbenzyl- °sO51... hlordan(e).ir1.2,4,5,,6,7,8,8-Octachioro-2,3,3a,4,7,- i piperazine; 1-[2'-(o-chlorobenzhydryloxy)ethyl]-4-(o-meth- 7a-hexahydro-4,7-methano-1H-indene; 1,2,4,5,6,7,8.8-octa- ` ylbenzyl)diethylenediamine; 1-(o-chlorobenzhydryloxyeth- chloro-3a,4,7,7a-tetra hyd ro-4,7-methanoindan; 1.2.4,5.6,7,- y1)-4-(o-methylbenzyl)piperazine; chlorbenzoxyethamine; 8.8-octachloro-4.7-methane-3a,4.7,7a-tetrahydroindane: , 1.! chlorobenzoxamine. C2,H 1CIN2O: mol wt 434.99. C CD-68; Velsicol 1.068:Toxichlor, Niran;Octachlor, Ortho- :, ', .- 74.54%, H 7.18%. Cl 8.15%, N 6.44%. 0 3.68%. Prepn: Klor.Synklor.Corodane:Belt. C,,H6CI,;mol wt 409.80. C , ¢y Morren et aL.Ind Chim.Be/ge22,409(1957);Monett.Brit. 29.31%. H 1.48%. CI 69.22%. The commercial product is a I, pat.837,986(1960). mixture containing 60 to 75%of the pure compound and 25 to 40% of related compds. Chlorine content: 64-67%. Cl 83C Prepn: Hyman. Brit. pat. 618,432 (1949); Kleiman. U.S. "1 , pat.2,598,561(1952 to Velsicol). i it CHOCH2C82 /--\ N—�2 it - > � COSs Cl Cl ��il� t� '- Cl. 'bill C1 . .....____....... . • boom 234-236'; booms 235'. - Dihydrochloride. CnH37C13N20, UCB 1474, Libratar, Cl° • 3. . '., ' :_.'-:;„ Antiulcera Master, Gastomax. Bitter crystals,mp 197-200'. I i _ Freely sol in methanol; sol in ethanol, chloroform. acetic ci acid:slightly sol in water,acetone. Practically insol in ace- tonitrile, ether, benzene. LDS, s.c.. i.v. in rats: 4000, 66 I � mg/kg;orally in mics: 1400 mg/kg. Levis et aL.Arch. Int Viscous,amber-colored liquid. Viscosity 69 poises at 25' _ Pharmacodyn. The,..118, 167(1959). (about that of 95%glycerol). Viscosity reduced considerably { i THERAP CAT: Anticholinergic. by heating to 120-140'F when it may be sprayed directly. 2049. Chlorbetamide. 2,2-Dichioro-N-[(2,4-dichloro- dss 1.59-1.63, nD 1.56.!.57. Insol in water,miscible with :t . - hen !)meth 1 N-(2-h aliphatic and aromatic hydrocarbon solvents, including p y y]- ydro(2-/i yl)acetethyl) 2.2-dichloro deodorized kerosene. Loses its chlorine in presence of alka- N-(2,4-dichlorobenzyl)-N-(2-hydroxyethyi)acetamide; N line reagents. and should not be formulated with any sal- (2.4-dichlorobenzy1)-N-(2-hydroxyethyl)dichloroacetamide; I, Win 5047; Mantomide: Pontalin. C11Ht,Q4NO2; mol wt vent, carrier. diluent or emulsifier• which has an alkaline 1 if, 331.05. C 39.91%,H 3.35%,a 42.84%,N 4.23%,0 9.67%. reaction. LDS,orally in rats: 457-590 mg/kg. I !i;x Note: The EPA has cancelled registrations of pesticides II: { rPrepn: Surrey,J.Am. Chem.Soc.76,2214(1954);U.S.pat. i containing this compound with the exception of its use 2,732,402(1956 to Sterling Drug). f' i through subsurface ground insertion for termite control and c1 the dipping of roots or tops of non-food plants: Fed Reg. G ' CH2CH2oR vol.40,p 28850(July 9, 1975). - I i I; 441 1 ttSE: Insecticide: Stomach poison. contact poison. fumi- I 4 Y Ci cU2xcocHci2 gant. See Bussart, Schor, Soap Sanit. Chemicals 24, 126 1 wti 1 t , (1948). Human Toxicity: Moderately irritating to skin. 11 s; Poisoning may occur by ingestion.inhalation,or percutane- I' •I li 1 i. Crystals from benzene + Skellysolve A.mp 112.4-113.4'. ous absorption. Acute Toxicity: Irritability, convulsions. 1 !; A I: E Slightly bitter taste. Very slightly sol in water,sol in 95% deep depression. Continued ingestion may cause degenera- 1 ) ` ethanol to at least 5%. tive changes in liver. • _ THERA?CAT: Amebicide. THERAP CAT(VET): Insecticide,acaricide- i tl 333 i 2050. Chlorcyclizine. 1-[(4-Chlorophenyl)phenylmeth- 2052. Chlordantoin. 5-(1-Ethylpentyl)-3-[(trichloro- { ' I. 'r yl]-4-methylpiperazine; 1-(p-chloro-a-phenylbenzyl)-4- methyl)thio]-2,4-imidazolidinedione; 5-(1-ethylpentyl)-3- 5 methylpiperazine; 1-(4-chlorobenzhydryl)-4-methylpipera- (trichloromethylthio)hydantoin; 5-(1-ethylamyl)-3-(trichlo- zinc; N-methyl-N'-(4-chlorobenzhydryl)piperazine; chloro- romethylthio)hydantoin; 3-(trichloromethylthio)-5-(1-eth- ' ! - t' cyclizine: compd 47-282; Alergicide: Perazyl; Trihistan. ylpentyl)hydantoin; 3-(trichloromethylthio)-5-(1-ethylam- ; } C15H21C1N2;mol wt 300.85. C 71.86%,H 7.04%.CI 11.79%, yl)hydantoin;Sporostacin. CI H17C13N 02S;mol wt 347.72. I�I! 'l q N 9.31%. Prepn: Baltzly et al.. J. Org. Chem. 14, 775 C 38.00%.H 4.93%,Cl 30.59%,N 8.06%.0 9.20%,S 9.22%. I { (1949); Murfitt. Dewing, Brit. pat. 656,043 (1951 to Well- Prepn of analogous compounds: Kittleson. Science 115, 84 it 1 come Found.);US.pat.2,630,435(1953 to Burroughs Well- (1952); cf..Kupferberg,Doscher, Antibiot 41 Chemother.11, j come). 73(1961). i :.1 .' I i h ca cl c2Hs 1: all I Y CN CH H 0 � is ,{ ® I CH3( 2)3 �/ �I : Cydp� H\SCClg 1 t CH3 THERAP CAT: Topical antifungal. ' s 2053. Chlordecone. Decachlorooctahydro-1,3,4-metheno- ' f Oil.bpo.ta,, 137-145'. 2H-cyciobuta[cdJpentalen-2-one;GC-1189; Kepone. Cr ( Y' Hydrochloride. C H C1 N. AH-289, Di-Paralene, Peru- CI 0: mol wt 490.68. C 24.48%, Cl 72.26%. 0 3.26%/. 1 W Y u 22 2 2 le I: sit Histantin (Burroughs Wellcome). Cryst powder. mp Prepn: Gilbert.Giolito.U.S.pats.2,616,825 and 2,616,928 I: F. : , 3:x { 226-227'. One gram dissolves in about 2 ml water.in 11 ml (1952 to Allied Chem., reissue 24,435; 1958). Structure: ! � .',;+ ... : :.;._ ale, in about 4 ml chloroform. Practically insol in ether, McBee et aLr J. Am. Chem. Soc.78, 1511 (1956). Review: I benzene. Ungnade. McBee. Chem. Rev.58,249-320(1958). ,{ t" { Consult the cross index before using this section- Page 263 r III - - , [ 4511 Hepaxanthin 418 (1962). Reviews: A. B. Foster. A. J. Huggard, 'The Chemistry of Heparin"i M.L.Wolfrom,Ed.,Adnan Cary /N` bohydr.Chem,vol.10(Academic Press.New York. 1955)pp I 335-368;M.L.Wolfrom,"Heparin and Related Substances" ! ; in Polysaccharides in Biology.Trans. 4th Conf. 1958, G. F. �,-'-- Co0Cttq Springer. Ed. (Josiah Macy.Jr.. Found.. New York. 1959) N pp 115-157. Review of commercial manuf: Mfg. Chem.34, 510(Nov. 1963). Annotated bibliography: M.M.Fishman, COOCH2C(CH2)5C83 Heparin and Lipid Metabolism(Tech. Service Labs., River I . Edge,NJ.. 1966) 1004 refs. f CI- Coocti2 ; mon mem coon aroax 2 K : ",I--o s " �" c..01)2 "" �" Crystals from ethanol. cop 94-96'. LD,orally in mice•. '. -� : i I _p-�I " _0_��"_ "/_0.- n --0-. On n _o_ >T61igExkP CAT: Peripheral vasodilator. I" I 11112 " Off " 4513. Heptabarbital. 5-(1-Cyclohepten-l-y1)-5-ethyl_ 2,4,6(1H,3H,5H)-pyrimidinetrione,5-(1-cyclohepten-l-y1)-5- desulfated heparin ethylbarbituric acid;5-ethyl-5-cycloheptenylbarbituric acid; Heptadorm; Medomin. C Hi5N202; mol wt 250.29. C { 62.38%, H 7.25%, N 11.19%, 0 19.18%. Prepn: Fr. pat. i 870,714(1942 to Geigy);Taub.US.pat.2,501,551(1950). k Heparin has a rotation of[alp +55'. Calcium salt, Calciparine -- N Magnesium salt, magnesium heparinate,Cutheparine. Sol 0, N�0 ;,, in water;insol in organic solvents. - Potassium salt. Ciarin. NH • T . I i,r Sodium salt. heparin sodium, Liquemin, Lipo-Hepinette, 1111x C * Longheparin, Pularin, Liquuemin Sodium, Thromboliquine. 5 2 a 1 '',t; White to grayish-brown amorphous powder. Odorless. I, a, hygroscopic. [a]if +47' (c = 1.5 in water). Absorption - h :i 17" spectrum: Burson et aL.J.Am. Chem Soc.78,5874(1956). Crystals. mp 174'. Slightly bitter taste uv max ( ore One gram dissolves in 20 ml water. Sol in saline soln:prac- NaOH): 218.5,254 am. Very sparingly sof in water,more 0.2N l • sol in alcohol. At 25'100 ml of sola contains: 4.0 g in alco- ., tically insol in alcohol.acetone,benzene.chloroform,ether. hof;5.7 g in acetone; 1.4 g.in chloroform. Soluble in alk,-• li,,;,-Iv: pH of 1%aq soln = 6.0 to 7.5. The potency calcd on the line solns. Forms water-soluble sodium, magnesium. and F dried basis is not less than 120 U.S.P.heparin units per mg. calcium salts. gn i Ampuled sofas may be stored at room temp for at least 12 !' 1 t i !j' months. Commercially available ampuled. sterile solns Caution: Abuse may lead to habituation or addiction. ' i �l!i contain 0.5%phenol or chlorobutanol as preservative. THERAP CAT: Hypnotic.sedative 1�{}I 1I'' THERAP CAT: Anticoagulant. Potassium salt as antihyper- _ eo' 1 4,5,6,7,8,8-Heptaehloro-3a,4,7,7a- t i li I' Epidemic. . termhydro-4,7-methanoindene;E 3314;Velsicol 104;Drinox: ; i ( • : ; THERAP CAT(vim: Anticoagulant. Heptamul. C„,IisCI,mol wt 373.35. C 32.17% H 1.35%, 'sl Ir 4511. He anthin. 5,6-E Cl 66.48%. Prepn: Bluestone et a1. U.S. pat. 2,576,666 : Pelt pony-5,6-dfhydroretinol;5,6- (1951 to Julius Hyman); McKenna et al.US.pat. 2,661,- + ;y. epoxide; -chromogen. I i• �+; C.2°113602;monoepoxyvitamin A; vitamin A eid574,o02;mol wt-302.44. C 79.42%.H 10.00%,O 10.58%. 377-8(1953 to Shell); Kleiman,Tapas, US.pat.2,904,599 1 i 1,. ,/1!;." Isola from cod liver oil and formation from vitamin A: (1959 to Velsicol). t{ i t!1 Karver. Jucker, Hely. Chico Acta 28, 717 (1945); 30, 559.6. f; i 4 m ( 1947). Preps and properties: Jungalwala.Cama. Biochem CI Ci J.95, 17(1965). See also Lakshanan et aL.ibid.27;Tsu- Cl j J.kids et al, Vitaminol 14,95(1968). ,/� tf• � k i' [ CI :11 r_ cl j H3C Cy -. ... {1 i".li. 0 3 "3 I d \ \ \ \ CHOHCrystals.mp 95-96'. Vapor pressure at 25' a 3 X 10-i I 1 t CHmm Hg. carbon in tetrachloride l solvent l n at 27': acetone 75,ben- 1 ,'L I cyclohexanone 119,alto- t `1 ' Cx3 hal 4.5,xylene 102. LD„orally in rats: 90 mg/kg. ill • Note The EPA has cancelled registration of pesticides 1 r" containing this compound with the exception of its use t through subsurface ground insertion for termite control and I, (. - the dipping of roots or tops of non-food plants, Fed. Reg. ( `CO: V Viscous yellow oil. uv max(ethanol): 272 nm. Freely sol voL 40,p 28850(July 9. 1975). a in chloroform. ether, benzene. Moderately sol in alcohol. USE: Insecticide for control of cotton boll weevil. Caution: r i t!i Slightly sol in petr ether. Poisoning may occur by ingestion,inhalation.skin contain- ination. Stimulates CNS;depression and anal i 4512. Hepronicate. Nicotinic acid triester with 2-hexyl- eP paralysis may fol- low. Liver damage is a possible late manifestation.Gleason I F j • 2-(hydroxymethyl)-1,3-propanediol;2-hexyl-2-(hydroxy- et al.. Clinical Toxicology of Commercial Pruducts(Williams methyl)-1.3-propanediol trinicotinate; 2.2-dihydroxymeth- + ,. &Wilkins.Baltimore,3rd ed., 1969)sect.III.p 120. i yl-n-octanoi trinicotinate; 1.1.1-trimethylolheptane trinico- tinate; 1.1.1-(trihydroxymethyl)heptane trinicotinate; Me- 4515. 2-(Heptadecenyl)-2-imidazoline-l-ethanol. 1-(2- li •r grin. H N O;mol wt 505.58. 6 _ Cts sr sC 6.52%, H 6.18%, N Hydroxyethyl)-2-heptadeernyl-2 imidazoline; 1-hydroxy- E l . ` 8.31%,0 18.99%. Preparation: Nakanishi et aL.Neth, yl-2-heptadeceaylglyoxalidiae; Nalcamine G-13. C2t- a i, ' r{ Appl. 6,514,807 torr pa o US.pat.3,384,64 Japan.pat. eth �t ' 10,988('67),(1966. 1968 and 196all to Yoshitomi). Pro- 4.56%.t. Prepn: Wilson,US.7pat.2,267,965 5.37%,H 12 08%,N 7.99%,0 t 1,f-,1 (1942 to Carbide ii uct monograph: Drugs of Today VIII.313(1972). and Carbon Chem.). 1 i Page 608 Consult the cross index before using this section. I1 - 1 ' ! ' : • Elii. i j ai,',.7.----, .,,• a ? r ., _ F:- `' iNYy•*v ,' �' . ��` .N c C W1- '' "=" 4---*-...:5